An analytical chemist has determined by measurements that there are moles of magnesium in a sample of talc. how many moles of si
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Answer:
0.3229 M HBr(aq)
0.08436M H₂SO₄(aq)
Explanation:
<em>Stu Dent has finished his titration, and he comes to you for help with the calculations. He tells you that 20.00 mL of unknown concentration HBr(aq) required 18.45 mL of 0.3500 M NaOH(aq) to neutralize it, to the point where thymol blue indicator changed from pale yellow to very pale blue. Calculate the concentration (molarity) of Stu's HBr(aq) sample.</em>
<em />
Let's consider the balanced equation for the reaction between HBr(aq) and NaOH(aq).
NaOH(aq) + HBr(aq) ⇄ NaBr(aq) + H₂O(l)
When the neutralization is complete, all the HBr present reacts with NaOH in a 1:1 molar ratio.
<em>Kemmi Major also does a titration. She measures 25.00 mL of unknown concentration H₂SO₄(aq) and titrates it with 0.1000 M NaOH(aq). When she has added 42.18 mL of the base, her phenolphthalein indicator turns light pink. What is the concentration (molarity) of Kemmi's H₂SO₄(aq) sample?</em>
<em />
Let's consider the balanced equation for the reaction between H₂SO₄(aq) and NaOH(aq).
2 NaOH(aq) + H₂SO₄(aq) ⇄ Na₂SO₄(aq) + 2 H₂O(l)
When the neutralization is complete, all the H₂SO₄ present reacts with NaOH in a 1:2 molar ratio.
Answer:
- pKa = 7.46
Explanation:
<u>1) Data:</u>
a) Hypochlorous acid = HClO
b) [HClO} = 0.015
c) pH = 4.64
d) pKa = ?
<u>2) Strategy:</u>
With the pH calculate [H₃O⁺], then use the equilibrium equation to calculate the equilibrium constant, Ka, and finally calculate pKa from the definition.
<u>3) Solution:</u>
a) pH
- pH = - log [H₃O⁺]
- 4.64 = - log [H₃O⁺]
b) Equilibrium equation: HClO (aq) ⇄ ClO⁻ (aq) + H₃O⁺ (aq)
c) Equilibrium constant: Ka = [ClO⁻] [H₃O⁺] / [HClO]
d) From the stoichiometry: [CLO⁻] = [H₃O⁺] = 2.29 × 10 ⁻⁵ M
e) By substitution: Ka = (2.29 × 10 ⁻⁵ M)² / 0.015M = 3.50 × 10⁻⁸ M
f) By definition: pKa = - log Ka = - log (3.50 × 10 ⁻⁸) = 7.46