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san4es73 [151]
2 years ago
15

The shape of an atomic orbital is associated with

Chemistry
1 answer:
Diano4ka-milaya [45]2 years ago
8 0

The properties of the atomic orbital are actually dependent on the quantum numbers.

size of atomic orbital: governed by the principal quantum number (n)

shape of atomic orbital: governed by the angular momentum quantum number (l)

orientation in space: governed by the magnetic quantum number (ml)

 

Since we are asked about the shape, hence the correct answer is:

angular momentum quantum number (l)

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Determine Z and V for steam at 250°C and 1800 kPa by the following: (a) The truncated virial equation [Eq. (3.38)] with the foll
makvit [3.9K]

Answer:

Explanation:

Given that:

the temperature T_1 = 250 °C= ( 250+ 273.15 ) K = 523.15 K

Pressure = 1800 kPa

a)

The truncated viral equation is expressed as:

\frac{PV}{RT} = 1 + \frac{B}{V} + \frac{C}{V^2}

where; B = - 152.5 \ cm^3 /mol   C = -5800 cm^6/mol^2

R = 8.314 × 10³ cm³ kPa. K⁻¹.mol⁻¹

Plugging all our values; we have

\frac{1800*V}{8.314*10^3*523.15} = 1+ \frac{-152.5}{V} + \frac{-5800}{V^2}

4.138*10^{-4}  \ V= 1+ \frac{-152.5}{V} + \frac{-5800}{V^2}

Multiplying through with V² ; we have

4.138*10^4  \ V ^3 = V^2 - 152.5 V - 5800 = 0

4.138*10^4  \ V ^3 - V^2 + 152.5 V + 5800 = 0

V = 2250.06  cm³ mol⁻¹

Z = \frac{PV}{RT}

Z = \frac{1800*2250.06}{8.314*10^3*523.15}

Z = 0.931

b) The truncated virial equation [Eq. (3.36)], with a value of B from the generalized Pitzer correlation [Eqs. (3.58)–(3.62)].

The generalized Pitzer correlation is :

T_c = 647.1 \ K \\ \\ P_c = 22055 \  kPa  \\ \\ \omega = 0.345

T__{\gamma}} = \frac{T}{T_c}

T__{\gamma}} = \frac{523.15}{647.1}

T__{\gamma}} = 0.808

P__{\gamma}} = \frac{P}{P_c}

P__{\gamma}} = \frac{1800}{22055}

P__{\gamma}} = 0.0816

B_o = 0.083 - \frac{0.422}{T__{\gamma}}^{1.6}}

B_o = 0.083 - \frac{0.422}{0.808^{1.6}}

B_o = 0.51

B_1 = 0.139 - \frac{0.172}{T__{\gamma}}^{ \ 4.2}}

B_1 = -0.282

The compressibility is calculated as:

Z = 1+ (B_o + \omega B_1 ) \frac{P__{\gamma}}{T__{\gamma}}

Z = 1+ (-0.51 +(0.345* - 0.282) ) \frac{0.0816}{0.808}

Z = 0.9386

V= \frac{ZRT}{P}

V= \frac{0.9386*8.314*10^3*523.15}{1800}

V = 2268.01 cm³ mol⁻¹

c) From the steam tables (App. E).

At T_1 = 523.15 \  K \ and  \ P = 1800 \ k Pa

V = 0.1249 m³/ kg

M (molecular weight) = 18.015 gm/mol

V  =  0.1249 × 10³ × 18.015

V = 2250.07 cm³/mol⁻¹

R = 729.77 J/kg.K

Z = \frac{PV}{RT}

Z = \frac{1800*10^3 *0.1249}{729.77*523.15}

Z = 0.588

3 0
2 years ago
Website
vredina [299]

Answer:

volume in L = 0.25 L

Explanation:

Given data:

Mass of Cu(NO₃)₂ = 2.43 g

Volume of KI = ?

Solution:

Balanced chemical equation:

2Cu(NO₃)₂  + 4KI    →    2CuI + I₂ + 4KNO₃

Moles of Cu(NO₃)₂:

Number of moles = mass/ molar mass

Number of moles = 2.43 g/ 187.56 g/mol

Number of moles = 0.013 mol

Now we will compare the moles of Cu(NO₃)₂ with KI.

                        Cu(NO₃)₂       :              KI    

                              2              :               4

                            0.013          :            4 × 0.013=0.052 mol

Volume of KI:

<em>Molarity = moles of solute / volume in L</em>

volume in L = moles of solute /Molarity

volume in L =  0.052 mol / 0.209 mol/L

volume in L = 0.25 L

6 0
2 years ago
A bottle containing 1,665 g of sulfuric acid (H2SO4, 98.08 g/mol) was spilled in a laboratory. The emergency spill kit contained
Tamiku [17]

Answer:

A. Yes, there is more than enough sodium carbonate.

Explanation:

Hello,

In this case, based on the given reaction which is:

H_2SO_4(aq) + Na_2CO_3(s) \rightarrow  Na_2SO_4(aq) + CO_2(g) + H_2O(l)

By stoichiometry, one computes the grams of sodium carbonate that will neutralize 1,665 g of sulfuric acid as shown below:

1,665gH_2SO_4*\frac{1molH_2SO_4}{98.08gH_2SO_4}*\frac{1molNa_2CO_3}{1molH_2SO_4} *\frac{105.99gNa_2CO_3}{1molNa_2CO_3}*\frac{1kgNa_2CO_3}{1000gNa_2CO_3}\\m_{Na_2CO_3}=1.80gNa_2CO_3

Thus, the available mass is 2.0 kg so 0.2 kg are in excess, therefore: A. Yes, there is more than enough sodium carbonate.

Best regards.

5 0
2 years ago
During a lab experiment performed at STP conditions, you prepare HCl by reacting 100. ml of Cl2 gas with an excess of H2 gas.
Brrunno [24]

Answer: 19.4 mL Ba(OH)2

Explanation:

H2(g) + Cl2(g) --> 2HCl(aq) (make sure this equation is balanced first)

At STP, 1 mol gas = 22.4 L gas. Use this conversion factor to convert the 100. mL of Cl2 to moles.

0.100 L Cl2 • (1 mol / 22.4 L) = 0.00446 mol Cl2

Use the mole ratio of 2 mol HCl for every 1 mol Cl2 to find moles of HCl produced.

0.00446 mol Cl2 • (2 mol HCl / 1 mol Cl2) = 0.00892 mol HCl

HCl is a strong acid and Ba(OH)2 is a strong base so both will completely ionize to release H+ and OH- respectively. You need 0.00892 mol OH- to neutralize all of the HCl. Note that one mole of Ba(OH)2 contains 2 moles of OH-.

0.00892 mol OH- • (1 mol Ba(OH)2 / 2 mol OH-) • (1 L Ba(OH)2 / 0.230 M Ba(OH)2) = 0.0194 L = 19.4 mL Ba(OH)2

3 0
2 years ago
The volume of hcl gas required to react with excess ca to produce 11.4 l of hydrogen gas at 1.62 atm and 62.0 °c is ________ l.
seropon [69]

Answer:

22.8 L  

Step-by-step explanation:

We can use <em>Gay-Lussac's Law of Combining Volumes</em> to solve this problem:

Gases <em>at the same temperature and pressure</em> react in simple whole-number ratios.

1. Write the chemical equation.

Ratio:                 2 L                             1 L

          Ca(s) + 2HCl(g) ⟶ CaCl₂(s) + H₂(g)

V/L:                                                     11.4

2. Calculate the volume of HCl.

According to the law, 2 L of HCl form 1 L of H₂.

Then, the conversion factor is (2 L HCl/1 L H₂).

Volume of HCl = 11.4 L H₂ × (2 L HCl/1 L H₂)

                         = 22.8 L HCl

3 0
2 years ago
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