Answer:
A = 674.33mmHg
B = 0.385atm
Explanation:
Both question A and B requires the application of pressure law which states that the pressure of a fixed mass of gas is directly proportional to its temperature provided that volume is kept constant.
Mathematically,
P = kT, k = P / T
P1 / T1 = P2 / T2 = P3 / T3 =.......= Pn/Tn
A)
Data:
P1 = 799mmHg
T1 = 50°C = (50 + 273.15) = 323.15K
P2 = ?
T2 = 273.15K
P1 / T1 = P2 / T2
Solve for P2
P2 = (P1 × T2) / T1
P2 = (799 × 273.15) / 323.15
P2 = 674.37mmHg
The final pressure is 674.37mmHg
B)
P1 = 0.470atm
T1 = 60°C = (60 + 273.15)K = 333.15K
P2 = ?
T2 = 273.15K
P1 / T1 = P2 / T2
Solve for P2,
P2 = (P1 × T2) / T1
P2 = (0.470 × 273.15) / 333.15
P2 = 0.385atm
The final pressure is 0.385atm
Answer : The final temperature would be, 791.1 K
Explanation :
According to the Arrhenius equation,

or,
![\log (\frac{K_2}{K_1})=\frac{Ea}{2.303\times R}[\frac{1}{T_1}-\frac{1}{T_2}]](https://tex.z-dn.net/?f=%5Clog%20%28%5Cfrac%7BK_2%7D%7BK_1%7D%29%3D%5Cfrac%7BEa%7D%7B2.303%5Ctimes%20R%7D%5B%5Cfrac%7B1%7D%7BT_1%7D-%5Cfrac%7B1%7D%7BT_2%7D%5D)
where,
= rate constant at
= 
= rate constant at
= 
= activation energy for the reaction = 265 kJ/mol = 265000 J/mol
R = gas constant = 8.314 J/mole.K
= initial temperature = 
= final temperature = ?
Now put all the given values in this formula, we get:
![\log (\frac{4\times K_1}{K_1})=\frac{265000J/mol}{2.303\times 8.314J/mole.K}[\frac{1}{733K}-\frac{1}{T_2}]](https://tex.z-dn.net/?f=%5Clog%20%28%5Cfrac%7B4%5Ctimes%20K_1%7D%7BK_1%7D%29%3D%5Cfrac%7B265000J%2Fmol%7D%7B2.303%5Ctimes%208.314J%2Fmole.K%7D%5B%5Cfrac%7B1%7D%7B733K%7D-%5Cfrac%7B1%7D%7BT_2%7D%5D)

Therefore, the final temperature would be, 791.1 K
The question is missing the graphics required to answer which I have attached as an image.
There are four different representations of the orientation of water molecules around chloride anion. Let's first analyze the water molecule.
We have H-O-H as the structure of water. The oxygen atom is more electronegative than the hydrogen atoms, which results in a partial positive charge on the hydrogen atoms and a partial negative charge on the oxygen atom.
The chloride anion is a negative charge. Therefore, the water molecules should orient themselves with the hydrogen atoms facing the chlorine atom as the partial positive charge on the hydrogen atoms will be attracted to the negative charge of the chlorine atom.
The correct representation is shown in graph 3 which shows all hydrogen atoms facing the chlorine anion.