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slamgirl [31]
2 years ago
6

Which of the following trends is indirectly proportional to effective nuclear charge, Zeff

Chemistry
2 answers:
Julli [10]2 years ago
7 0

Answer : Option C) Atomic Size

Explanation : The atomic radius of the elements is found to be decreasing if we go from left to right in the modern periodic table. Accordingly, Z_{eff} increases as the number of shielding electrons present in the atomic nucleus of the periodic elements which lies in the same row remains constant while the number of protons in each atomic shell increases.

The effective nuclear charge Z_{eff} of an atom is defined as the net positive charge which is felt by the valence electron of the atomic element.

When Z_{eff} is observed to decrease, it is seen that the atomic radius grows in size. So, it explains the inverse relationship between both. This phenomenon occurs, because there is more screening of the electrons from the nucleus taking place, which is observed due to decrease the attraction between the electron and the nucleus.

ra1l [238]2 years ago
3 0

Periodic trends provides information about an element’s properties. One major trends in the periodic table is the atomic size, which is indirectly proportional to effective nuclear charge. The atomic size gradually decreases from left to right across a periodic table because all electrons are added to the same shell. At the same time, protons are also added to the nucleus, making it more positively charged.

Due to this, there is a greater nuclear attraction; the effect of increasing proton number is greater than that of the increasing electron number, which means that there is a strong attraction of nucleus manifested by pulling the atom's shell closer to the nucleus. Then, the valence electrons are seized closer towards the nucleus of the atom, which resulted to the decrease in atomic radius.

 


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Assuming equal concentrations and complete dissociation, rank these aqueous solutions by their freezing points. NH4l, CoBr3, Na2
seraphim [82]
Answer:

NaI > Na2SO4 > Co Br3

meaning that NaI has the highest freezing point, and Co Br3 has the lowest freezing point.

Explanation:

The freezing point depression is a colligative property.

That means that it depends on the number of solute particles dissolved.

The formula to calculate the freezing point depression of a solution of a non volatile solute is:

ΔTf = i * Kf * m

Where kf is a constant, m is the molality and i is the van't Hoff factor.

Molality, which is number of moles per kg of solvent, counts for the number of moles dissolved and the van't Hoff factor multipllies according for molecules that dissociate.

The higher the number of molecules that dissociate, the higher the van't Hoff, the greater the freezing point depression and the lower the freezing point.

As the question states that you assume equal concentrations (molality) and complete dissociation you just must find the number of ions generated by each solute, in this way:

NH4 I → NH4(+) + I(-) => 2 ions

Co Br3 → Co(+) + 3 Br(-) => 4 ions

Na2SO4 → 2Na(+) + SO4(2-) => 3 ions.

So, Co Br3 is the solute that generate more particles and that solution will exhibit the lowest freezing point among the options given, Na2SO4 is next and the NaI is the third. Ordering the freezing point from higher to lower the rank is NaI > Na2SO4 > CoBr3, which is the answer given.
4 0
1 year ago
a 75.0 liter canister contains 15.82 moles of argon at a pressure of 546.8 kilopascals. What is the temperature of the canister?
abruzzese [7]

Pressure of argon = 546.8 kPa

Conversion factor: 1 atm = 101.325 kPa

Pressure of argon = 546.8 kPa x 1 atm/101.325 kPa = 5.4 atm

Moles of argon = 15.82

Volume of argon = 75.0 L

According to Ideal gas law,

PV = nRT

where P is the pressure, V is the volume , n is the number of moles, R is the universal gas constant, and T is the temperature

T = PV/nR = (5.4 atm x 75.0 L) / (15.82 x 0.0821 L.atm.mol⁻¹K⁻¹)

T = 311.82 K

Hence the temperature of the canister is 311.82 K.

4 0
2 years ago
Complete the following sentence: The cathode in a voltaic cell is the electrode _____________.
Sergio [31]

Answer:

to which cations from the salt bridge migrate

Explanation:

A voltaic cell is an electrochemical cell that uses spontaneous redox reactions to generate electricity. It's composed of a cathode, an anode, and a salt bridge.

In cathode, the substance is gaining electrons, so it's reducing, in the anode, the substance is losing electrons, so it's oxidating. The flow of electrons is from the anode to the cathode.

The salt bridge is a bond between the cathode and the anode. When the redox reaction takes place, the substances produce its ions, so the solution is no more neutral. The salt bridge allows the solutions to become neutral and the redox reaction continues.

So, the cathode produces anions, which goes to the anode, and the anode produces cations, which goes to the cathode. Then, the cathode n a voltaic cell is the electrode to which cations from salt bridge migrate and where the reduction takes place.

7 0
2 years ago
Which of the following statements are True about the experimental process used in the Diels Alder reaction?
vovikov84 [41]

Here we have to get the correct statements among the given, applicable for Diels-Alder reaction.

The true statements in case Diels-Alder reaction are-

1. An excess of Maleic anhydride is used.

2. The I.R. of the products are indistinguishable.

The Diels-Alder reaction is the most is the most important cyclo-addition reaction in organic chemistry. These are addition reactions in which ring systems are formed without eliminating any compounds.

There remains one diene and one dienophile. The reaction is reversible in nature and requires elevated temperature to obtain its transition state. The reaction rate become faster in certain condition like using of polar solvents.

Among the given statements the following statements are true-

1. An excess of maleic anhydride (the most effective di-enophile) is used to process the reaction in forward direction.

2. The products obtain in this reaction are stereoisomers thus are indistinguishable by infrared spectroscopy (IR).

The statements which are not true for the Diels-Alder reaction:

3. The re-crystallization of the products by any polar solvent like methanol is not feasible as it will cause the retro reaction due to stability of the transition state in polar solvent.

4. Cleaning of glassware are compulsory for any reaction it is not specifically true for Diels-Alder reaction.

5. The reaction occurs at elevated temperature thus flame is required.

 

8 0
1 year ago
El cuerpo humano tiene unos 6 billones de células (6,0x1012) y la población de la Tierra es de unos 8 000 millones de personas.
zloy xaker [14]

Answer:

En toda la población del mundo hay <u>0.0797 moles de células</u>

Explanation:

1.0 mol of cells = 6.022 * 10∧23 cells

X mol of cells  = 6.0 * 10∧12 cells

- X is cleared to find out how many moles of cells are in a human body:

  • X = 6.0 * 10∧12 cells / 6.022 * 10∧23 cells
  • X = 9,963 * 10∧-12 moles of cells per person

In the world there are 8 * 10∧9 people, how many moles in total will there be?

8 * 10∧9 people * 9,963 * 10∧-12 moles of cells per person  =

<u>0.0797 moles of molecules in the entire population of the earth.</u>

4 0
2 years ago
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