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Alla [95]
2 years ago
5

What is the ph of a solution of 0.400 m k2hpo4, potassium hydrogen phosphate?

Chemistry
1 answer:
dusya [7]2 years ago
3 0
When we can get Pka for K2HPO4 =6.86 so we can determine the Ka :

when Pka = - ㏒ Ka

          6.86 = -㏒ Ka 

∴Ka = 1.38 x 10^-7

by using ICE table:

               H2PO4- →  H+  + HPO4
initial      0.4 m            0         0

change     -X                +X       +X

Equ       (0.4-X)               X          X

when Ka = [H+][HPO4] / [H2PO4-]

by substitution:

1.38 X 10^-7 = X^2 / (0.4-X)   by solving for X

∴X = 2.3x 10^-4 

∴[H+] = X = 2.3 x 10^-4

∴PH = -㏒[H+]

        = -㏒ (2.3 x 10^-4)
 ∴PH  =  3.6

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Answer : The resulting concentration of Na^+ ion is, 4.5 M

Explanation : Given,

Concentration of Na_2CO_3 = M_1 = 3.0 M = 3.0 mol/L

Volume of Na_2CO_3 = V_1 = 70 mL = 0.07 L

Concentration of NaHCO_3 = M_2 = 1.0 M = 1.0 mol/L

Volume of NaHCO_3 = V_2 = 30 mL = 0.03 L

First we have to calculate the moles of Na_2CO_3 and NaHCO_3

\text{Moles of }Na_2CO_3=\text{Concentration of }Na_2CO_3\times \text{Volume of }Na_2CO_3=3.0mol/L\times 0.07L=0.21mol

and,

\text{Moles of }NaHCO_3=\text{Concentration of }NaHCO_3\times \text{Volume of }NaHCO_3=1.0mol/L\times 0.03L=0.03mol

Now we have to calculate the moles of Na^+ ions.

As, 1 mole of Na_2CO_3 will give 2 moles of Na^+ ions

So, 0.21 moles of Na_2CO_3 will give 2\times 0.21=0.42 moles of Na^+ ions

and,

As, 1 mole of NaHCO_3 will give 1 mole of Na^+ ions

So, 0.03 moles of NaHCO_3 will give 0.03 moles of Na^+ ions

So,

Total number of moles of Na^+ ions = 0.42 + 0.03 =0.45 mole

Total volume of both solution = 70 mL + 30 mL = 100 mL = 0.1 L

Now we have to calculate the concentration of Na^+ ions.

\text{Concentration of }Na^+=\frac{\text{Moles of }Na^+}{\text{Volume of solution}}=\frac{0.45mol}{0.1L}=4.5mol/L=4.5M

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6 0
2 years ago
Which nuclear emission moving through an electric field would be deflected toward the positive electrode?
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Gamma rays are often used to kill microorganisms in food, in an attempt to make the food safer. Some people contend that this ir
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Answer:

b . Irradiated food is shown to not be radioactive.

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If it can be proven that irradiated food is not radioactive, then it will effective dispute the idea that irradiated food are less safe to eat.

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4 0
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29. A certain nut crunch cereal contains 11.0 grams of sugar (sucrose, C12H22O11) per serving size of 60.0 grams. How many servi
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Explanation:

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We have 0.032 mol of sucrose in a serving of 60 g. But we need less moles (0.0278 mol):

0.032 mol ------------ 60 g serving

0.0278 mol------------ x= 0.0278 mol x 60 g serving/0.032 mol

                                x= 51.8 g

So,  lesser than 1 serving of 60 g must be eaten to consume 0.0278 mol os sucrose. Exactly, 51.8 g (which stands for a 86% of the serving size).

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