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xenn [34]
2 years ago
14

Which of the following shows the correct rearrangement of the the heat equation q = mCpΔT to solve for specific heat?

Chemistry
2 answers:
strojnjashka [21]2 years ago
6 0
When 
q = m*Cp*ΔT

when q is Heat energy in Joules

and m is the mass of the substance in Kg

and Cp is the specific heat (J/Kg.K)

and Δ T is the change in temperature in Kelvin


so, by rearranging the formula we can get the specific heat Cp from:

∴Cp = q / m*ΔT
Kipish [7]2 years ago
5 0

Answer:

C_{p} = \frac{q}{m(deltaT)}

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<u>Answer:</u>

<u>For A:</u> The free energy change of the reaction is -5339.76 J/mol

<u>For B:</u> The units of free energy change of the reaction are kJ/mol

<u>For C:</u> The forward reaction is favorable and reverse reaction is unfavorable.

<u>Explanation:</u>

For the given chemical reaction:

DHAP\rightleftharpoons G_3P

  • <u>For A:</u>

Relation between standard Gibbs free energy and equilibrium constant follows:

\Delta G^o=-RT\ln K_{eq}

To calculate the free energy change, we use the equation:

\Delta G=\Delta G^o+RT\ln Q

Or,

\Delta G=-RT^o\ln K_{eq}+RT\ln Q

where,

\Delta G = Free energy change

R = Gas constant = 8.314J/K mol

T^o = standard temperature = 25^oC=[273+25]K=298K

T = temperature of the cell = 37^oC=[273+37]K=310K

K_[eq} = equilibrium constant = 5.4\times 10^{-2}

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[G_3P] = 0.06 M

[DHAP] = 0.125 M

Putting values in above equation, we get:

\Delta G=[-(8.314J/mol.K\times 298K\times \ln (5.4\times 10^{-2}))]+[(8.314J/mol.K\times 310K\times \ln (\frac{0.06}{0.125}))]\\\\\Delta G=-[-7231.46]+[-1891.7]=-5339.76J/mol

Hence, the free energy change of the reaction is -5339.76 J/mol

  • <u>For B:</u>

Converting the free energy change of the reaction into kilojoules, we use the conversion factor:

1 kJ = 1000 J

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For the reaction to be spontaneous, the Gibbs free energy of the reaction must come out to be negative. But, from the above calculation, the Gibbs free energy of the reaction is positive. Thus, the reaction is non-spontaneous.

As, the free energy change of the reaction is negative.

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\frac{8.53}{293K}=\frac{10.4}{T_2}\\\\T_2=357K

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