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DENIUS [597]
2 years ago
4

Be sure to answer all parts. Nitroglycerin (c3h5n3o9) is a powerful explosive. Its decomposition may be represented by 4c3h5n3o9

→ 6n2 12co2 10h2o o2 this reaction generates a large amount of heat and gaseous products. It is the sudden formation of these gases, together with their rapid expansion, that produces the explosion. (a) what is the maximum amount of o2 in grams that can be obtained from 3.50 × 102 g of nitroglycerin
Chemistry
1 answer:
Anton [14]2 years ago
7 0

Answer : The maximum amount of O_{2} obtained = 12.576 g

Solution :  Given,

                Mass of Nitroglycerin C_{3} H_{5} N_{3} O_{9} = 3.50 × 102g

                Molar mass of Nitroglycerin C_{3} H_{5} N_{3} O_{9} = 227.0865 g/mol

First, find the number of moles of  Nitroglycerin i.e

Number of moles of Nitroglycerin = \frac{Given Mass}{Molar Mass}

                                                        = \frac{3.50\times 102g}{227.0865g/mol}

                                                        = 1.5720 moles

4C_{3} H_{5} N_{3} O_{9}\rightarrow 6N_{2}+12Co_{2}+10H_{2}O+O_{2}

According to reaction,

                   4 moles of Nitroglycerin gives 1 mole of Oxygen

  and,  1.5720 moles of Nitroglycerin gives    →  \frac{1}{4}\times 1.5720

                                                                            =  0.393 moles

    Now, we have to find the amount of Oxygen obtained.

     Formula used  :    

Weight of Oxygen obtained = Number of moles of Oxygen × Molar mass of oxygen

     Weight of Oxygen obtained = 0.393 moles × 32 g/mol

                                                     =  12.576 g


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<u>Answer:</u> The mass of ammonia produced is 28.22 g

<u>Explanation:</u>

To calculate the number of moles, we use the equation:

\text{Number of moles}=\frac{\text{Given mass}}{\text{Molar mass}}     .....(1)

  • <u>For hydrogen gas:</u>

Given mass of hydrogen gas = 10.0 g

Molar mass of hydrogen gas = 2 g/mol

Putting values in equation 1, we get:

\text{Moles of hydrogen gas}=\frac{10.0g}{2g/mol}=5mol

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Given mass of nitrogen gas = 80.0 g

Molar mass of nitrogen gas = 28 g/mol

Putting values in equation 1, we get:

\text{Moles of nitrogen gas}=\frac{80.0g}{28g/mol}=2.86mol

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N_2+3H_2\rightarrow 2NH_3

By Stoichiometry of the reaction:

3 moles of hydrogen gas reacts with 1 mole of nitrogen gas

So, 5 moles of hydrogen gas will react with = \frac{1}{3}\times 5=1.66mol of nitrogen gas

As, given amount of nitrogen gas is more than the required amount. So, it is considered as an excess reagent.

Thus, hydrogen gas is considered as a limiting reagent because it limits the formation of product.

By Stoichiometry of the reaction:

3 moles of hydrogen gas produces 1 mole of ammonia

So, 5 moles of hydrogen gas will produce = \frac{1}{3}\times 5=1.66moles of ammonia

Now, calculating the mass of ammonia from equation 1, we get:

Molar mass of ammonia = 17 g/mol

Moles of ammonia = 1.66 moles

Putting values in equation 1, we get:

1.66mol=\frac{\text{Mass of ammonia}}{17g/mol}\\\\\text{Mass of ammonia}=(1.66mol\times 17g/mol)=28.22g

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Ligands that cause a large crystal field splitting such as CN^- are called strong field ligands. They lead to the formation of diamagnetic species. Strong field ligands occur towards the end of the spectrochemical series of ligands.

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