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Komok [63]
2 years ago
15

Identify the oxidizing agent and the reducing agent in the following reactions: (i) 8NH3( g) + 6NO2( g) => 7N2( g) + 12H2O( l

) (ii) Zn(s) +AgNO3(aq) => Zn(NO3) 2(aq) + Ag(s) (unbalanced)
Chemistry
1 answer:
shusha [124]2 years ago
4 0

Answer:

(i)  Oxidizing Agent: NO2 / Reducing Agent NH3-

(ii) Oxidizing Agent AgNO3 / Reducing Agent Zn

Explanation:

(i) 8NH3( g) + 6NO2( g) => 7N2( g) + 12H2O( l)

In this reaction, both two reactants contain nitrogen with a different oxidation number and produce only one product which contains nitrogen with a unique oxidation state. So, nitrogen is oxidized and reduced in the same reaction.

Nitrogen Undergoes a change in oxidation state from 4+ in NO2 to 0 in N2. It is reduced because it gains electrons (decrease its oxidation state). NO2 is the oxidizing agent (electron acceptor).

Nitrogen Changes from an oxidation state of 3- in NH3 to 0 in N2. It is oxidized because it loses electrons (increase its oxidation state). NH3 is the reducing agent (electron donor)

(ii) Zn(s) +AgNO3(aq) => Zn(NO3)2(aq) + Ag(s)

Ag changes oxidation state from 1+ to 0 in Ag(s).

Ag is reduced because it gains electrons and for this reason and AgNO3 is the oxidizing agent (electron acceptor)

Zn Changes from an oxidation state of 0 in Zn(s) to 2+ in Zn(NO3)2. It is oxidized and for this reason Zn is the reducing agent (electron donor).

Balanced equation:

Zn(s) +2AgNO3(aq) => Zn(NO3)2(aq) + 2Ag(s)

 

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<u>Answer:</u> The ratio of carbon in both the compounds is 1 : 2

<u>Explanation:</u>

Law of multiple proportions states that when two elements combine to form two or more compounds in more than one proportion. The mass of one element that combine with a given mass of the other element are present in the ratios of small whole number. For Example: Cu_2O\text{ and }CuO

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Total mass of sample = 100 g

Mass of carbon = 27.2 g

Mass of oxygen = (100 - 27.7) = 72.8 g

To formulate the formula of the compound, we need to follow some steps:

  • <u>Step 1:</u> Converting the given masses into moles.

Moles of Carbon =\frac{\text{Given mass of Carbon}}{\text{Molar mass of Carbon}}=\frac{27.2g}{12g/mole}=2.26moles

Moles of Oxygen = \frac{\text{Given mass of oxygen}}{\text{Molar mass of oxygen}}=\frac{72.8g}{16g/mole}=4.55moles

  • <u>Step 2:</u> Calculating the mole ratio of the given elements.

For the mole ratio, we divide each value of the moles by the smallest number of moles calculated which is 2.26 moles.

For Carbon = \frac{2.26}{2.26}=1

For Oxygen  = \frac{4.55}{2.26}=2.01\approx 2

  • <u>Step 3:</u> Taking the mole ratio as their subscripts.

The ratio of C : O = 1 : 2

Hence, the formula for sample 1 is CO_2

  • <u>For Sample 2:</u>

Total mass of sample = 100 g

Mass of carbon = 42.9 g

Mass of oxygen = (100 - 42.9) = 57.1 g

To formulate the formula of the compound, we need to follow some steps:

  • <u>Step 1:</u> Converting the given masses into moles.

Moles of Carbon =\frac{\text{Given mass of Carbon}}{\text{Molar mass of Carbon}}=\frac{42.9g}{12g/mole}=3.57moles

Moles of Oxygen = \frac{\text{Given mass of oxygen}}{\text{Molar mass of oxygen}}=\frac{57.1g}{16g/mole}=3.57moles

  • <u>Step 2:</u> Calculating the mole ratio of the given elements.

For the mole ratio, we divide each value of the moles by the smallest number of moles calculated which is 3.57 moles.

For Carbon = \frac{3.57}{3.57}=1

For Oxygen  = \frac{3.57}{3.57}=1

<u>Step 3:</u> Taking the mole ratio as their subscripts.

The ratio of C : O = 1 : 1

Hence, the formula for sample 1 is CO

In the given samples, we need to fix the ratio of oxygen atoms.

So, in sample one, the atom ratio of oxygen and carbon is 2 : 1.

Thus, for 1 atom of oxygen, the atoms of carbon required will be = \frac{1}{2}\times 1=\frac{1}{2}

Now, taking the ratio of carbon atoms in both the samples, we get:

C_1:C_2=\frac{1}{2}:1=1:2

Hence, the ratio of carbon in both the compounds is 1 : 2

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