Answer:
See explanation
Explanation:
% optical purity = specific rotation of mixture/specific rotation of pure enantiomer * 100/1
specific rotation of mixture = 23°
specific rotation of pure enantiomer = 61°
Hence;
% optical purity = 23/61 * 100 = 38 %
More abundant enantiomer = 100% - 38 % = 62%
Hence the pure (S) carvone is (-) 62° is the more abundant enantiomer.
Enantiomeric excess = 62 - 50/50 * 100 = 24%
Hence
(R) - carvone = 38 %
(S) - carvone = 62%
Answer:
ΔH°c = -2219.9 kJ
Explanation:
Let's consider the combustion of propane.
C₃H₈(g) + 5 O₂(g) ⟶ 3 CO₂(g) + 4 H₂O(l)
We can find the standard enthalpy of the combustion (ΔH°c) using the following expression.
ΔH°c = [3 mol × ΔH°f(CO₂(g)) + 4 mol × ΔH°f(H₂O(l))] - [1 mol × ΔH°f(C₃H₈(g)) + 5 mol × ΔH°f(O₂(g))]
ΔH°c = [3 mol × (-393.5 kJ/mol) + 4 mol × (-285.8 kJ/mol)] - [1 mol × (-103.8 kJ/mol) + 5 mol × (0 kJ/mol)]
ΔH°c = -2219.9 kJ
1. Answer: C. The objects' temperatures have both changed by the same amount.
Explanation:
An object is said to be in thermal equilibrium when the objects have attained same temperature. Heat transfer from hotter object to colder one in contact takes place until the temperature of the two are equal. It is not necessary that the temperature of both the objects changes by same amount. After attainment of thermal equilibrium, the temperature of the objects stop changing and the tiny particles of the object move at the same rate.
Hence, the objects' temperatures have both changed by the same amount. is not necessarily true for two objects in thermal equilibrium.
2. Answer: C. Objects are made of tiny particles, and their motion depends on the temperature.
Explanation:
Kinetic theory of heat states that the kinetic energy of constituent particles determine the temperature of the object. The statement that best explains this is Objects are made of tiny particles, and their motion depends on the temperature.
Answer:
The atomic mass of second isotope is 7.016
Explanation:
Given data:
Average Atomic mass of lithium = 6.941 amu
Atomic mass of first isotope = 6.015 amu
Relative abundance of first isotope = 7.49%
Abundance of second isotope = ?
Atomic mass of other isotope = ?
Solution:
Total abundance = 100%
100 - 7.49 = 92.51%
percentage abundance of second isotope = 92.51%
Now we will calculate the mass if second isotope.
Average atomic mass of lithium = (abundance of 1st isotope × its atomic mass) +(abundance of 2nd isotope × its atomic mass) / 100
6.941 = (6.015×7.49)+(x×92.51) /100
6.941 = 45.05235 + (x92.51) / 100
6.941×100 = 45.05235 + (x92.51)
694.1 - 45.05235 = (x92.51)
649.04765 = x
92.51
x = 485.583 /92.51
x = 7.016
The atomic mass of second isotope is 7.016
Answer:
a. The atom will go from a two-dimensional configuration to a three dimensional configuration.
d. The bond angle will increase.
f. The number of unhybridized p orbitals will decrease.
Explanation:
Sp2 is the atomic bond in which orbitals mixes with only two orbitals. These orbitals form three sp2. When two carbon atoms are overlapped they form sigma bond by overlapping of sp2 bonds. Sp3 bond is created when there is one lone molecule available for combination. When the bonding is updated from sp2 to sp3 then unhybridized orbitals will decrease causing the bond angle to increase.
