Answer:
The incomplete and varying inversion of configuration takes place at the chirality center.
Explanation:
When optically active alcohols react with HBr an SN1 reaction occurs.
In SN1 reactions an intermediate carbocation is formed in which the nucleophile can attack it on either side of the molecule. Therefore, there is a partial inversion of the center of chilarity of the molecule.
Answer:
a. withdraws electrons inductively
b. donates electrons by hyperconjugation
c. donates electrons by resonance
d. withdraws electrons inductively
Explanation:
a. The bromide ion is a highly electronegative ion (in the halide series). Electronegative substituents on acids increase the acidity by inductive electron withdrawal method. The higher the electronegativity of a substance, the greater the acidity. The halogens have this order of electronegativity:
F > Cl > Br>I
b. The carboxyl groups have a stabilization of the sigma and pi bonds. This is achieved through a special delocalization of electrons. Because of the delocalization, hyperconjugation is the result effect.
c. The NHCH₃ group has a highly electonegative nitrogen atom that pulls the electron cloud towards itself. In this case, it withdraws electrons inductively. As a result, it donates electrons by resonance.
d. The OCH₃ group has a highly electonegative oxygen atom. This oxygen atom withdraws electron cloud towards itself. As a result, it withdraws electrons inductively.
Answer:
-3.7771 × 10² kJ/mol
Explanation:
Let's consider the following equation.
3 Mg(s) + 2 Al³⁺(aq) ⇌ 3 Mg²⁺(aq) + 2 Al(s)
We can calculate the standard Gibbs free energy (ΔG°) using the following expression.
ΔG° = ∑np . ΔG°f(p) - ∑nr . ΔG°f(r)
where,
n: moles
ΔG°f(): standard Gibbs free energy of formation
p: products
r: reactants
ΔG° = 3 mol × ΔG°f(Mg²⁺(aq)) + 2 mol × ΔG°f(Al(s)) - 3 mol × ΔG°f(Mg(s)) - 2 mol × ΔG°f(Al³⁺(aq))
ΔG° = 3 mol × (-456.35 kJ/mol) + 2 mol × 0 kJ/mol - 3 mol × 0 kJ/mol - 2 mol × (-495.67 kJ/mol)
ΔG° = -377.71 kJ = -3.7771 × 10² kJ
This is the standard Gibbs free energy per mole of reaction.
Answer: 0.548J/g°C
Explanation:
Q = s × m × DeltaT
Q = Heat (J)
S = Specific Heat Capacity
M = mass (g)
DeltaT = Change in temperature (°C)
0.158Kg x 1000 = 158g
2.510J = s x 158g x (61°C-32°C)
2.510J/(158g x 29°C) = s
S = 0.54779.... J/g°C
S = 0.548 J/g°C
Answer:
The correct answer is Option-D (6 Hydrogen atoms).
Explanation:
Carbon atom has a unique property of linking to it self and making a chain of carbon called as Catenation. In a molecule having two carbon atoms there must be a bond between the two carbon atoms. The bond can be saturated (single bond) or unsaturated (double or triple bond). But as the statement states maximum number of hydrogen atoms so, we will asume the bond between two carbon atoms to be single.
As carbon has four valence electrons so, it has the ability to make four single bonds. In given molecule each carbon has already made a single bond with another carbon therefore, each carbon is left with three more unpaired electrons which will make covalent bond with three hydrogen atoms each as shown in attached structure.
