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svetlana [45]
2 years ago
15

Part A Name the complex ion [Fe(CN)6]^3- . The oxidation number of iron is +3. Part B Name the complex ion [Cu(NH3)2(H2O)4]^2+ .

The oxidation number of copper is +2. Part C Name the complex CrCl2(en)2 . The oxidation number of chromium is +2. Part D Name the salt [Ni(H2O)3(Co)]SO4 . The oxidation number of nickel is +2. Part E Name the salt K4[Pt(CO3)2F2] given that the carbonate ion acts as a monodentate ligand in the complex. The oxidation number of platinum is +2.
Chemistry
1 answer:
zvonat [6]2 years ago
5 0

Answer:

Part A: Hexacyanoferrate (III)

Part B: DiammintetraaquoCupperate (II)

Part C: Dichlorobis(ethylenediamine) Chromate (II)

Part D: Triaquocarbonylnickel (II) Sulphate

Part E: Potassium Dicarbonatedifluoroplatinate (II)

Explanation:

For naming the complex ions there is a specific rule

Nomenclature of the complex ions are as follow

  • write a correct formulae
  • Indicate the oxidation number of metal in the complex
  • The oxidation number should write in the roman numeral in perenthasis after metal name
  • Ligand named before the metal ion
  • Ligan can be named in following order

                  * 1st negative,  2nd neutral, 3rd positive

                  * If there are more than 2 same charged ligand the write in                      

                    alphabetical order.

  • Write prefix i.e di, tri, tetra for multiple monodentate ligands
  • Anions name end at ido the replace the final name.
  • Neutral ligands named as their usual name, but there are some exceptions such as

                                      NH3 named as ammine

                                      H2O names aqua or aquo

                                     CO named ascarbonyl

                                      NO named as nitrosyl

  • If the complex is an anion, then name of the central atom will end in -ate, and its Latin name will be used except for mercury
  • The name of full complex will end with cation or anion with separate word.  

Keeping the rules in mind the complexes named as following.

_________________________

Part A:

[Fe(CN)₆]³⁻

Name of the Complex : Hexacyanoferrate (III)  

___________________

Part B:

[Cu(NH₃)₂(H₂O)₄]²⁺

Name of the Complex : DiammintetraaquoCupperate (II)

_______________________

Part C

CrCl₂(en)₂

Name of the Complex :  Dichlorobis(ethylenediamine) Chromate (II)

________________________

Part C

[Ni(H₂O)₃(CO)]SO₄

Name of the Complex : Tetraaquocarbonylnickel (II) Sulphate

______________________

Part E

K₄[Pt(CO₃)₂F₂]

Name of the Complex : Potassium Dicarbonatedifluoroplatinate (II)

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Gd → Gd⁺ + 1e⁻, Gd⁺ → Gd⁺² + 1e⁻, Gd⁺² → Gd⁺³ + 1e⁻

Explanation:

The ionization energy is the energy necessary to remove one electron of the atom, transforming it in a cation. The first ionization energy is the energy necessary to remove the first electron, the second energy, to remove the second electron, and then successively.

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Answer:

2 water + sugar + lemon juice → 4 lemonade

Moles of water present in 946.36 g of water=\frac{946.36 g}{236.59 g/mol}=4 mol=

236.59g/mol

946.36g

=4mol

Moles of sugar present in 196.86 g of water=\frac{196.86 g}{225 g/mol}=0.8749 mol=

225g/mol

196.86g

=0.8749mol

Moles of lemon juice present in 193.37 g of water=\frac{193.37 g}{257.83 g/mol}=0.7499 mol=

257.83g/mol

193.37g

=0.7499mol

Moles of lemonade in 2050.25 g of water=\frac{2050.25 g}{719.42 g/mol}=2.8498 mol=

719.42g/mol

2050.25g

=2.8498mol

As we can see that number of moles of lemon juice are limited.

So, we will consider the reaction will complete in accordance with moles of lemon juice.

1 mole lemon juice reacts with 2 mol of water,then 0.7499 mol of lemon juice will react with:

\frac{2}{1}\times 0.7499 mol = 1.4998 mol

1

2

×0.7499mol=1.4998mol of water

Mass of water used = 1.4998 mol × 236.59 g/mol=354.8376 g

Water remained unused = 946.36 g - 354.8376 g =591.5223 g

1 mole lemon juice reacts with mol of sugar,then 0.7499 mol of lemon juice will react with:

\frac{1}{1}\times 0.7499 mol = 0.7499 mol

1

1

×0.7499mol=0.7499mol of water

Mass of sugar used = 0.7499 mol × 225 g/mol = 168.7275 g

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1 mole of lemon juice gives 4 moles of lemonade.

Then 0.7499 mol of lemon juice will give:

\frac{4}{1}\times 0.7499 mol=2.996 mol

1

4

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Theoretical yield of lemonade = 2157.9722 g

Experimental yield of lemonade = 2050.25 g

Percentage yield of lemonade:

\frac{\text{Experimental yield}}{\text{theoretical yield}}\times 100

theoretical yield

Experimental yield

×100

\frac{2050.25 g}{2157.9722 g}\times 100=95.00\%

2157.9722g

2050.25g

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Mathematically, we have :

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Normality N = 0.2 N

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