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Bingel [31]
2 years ago
14

A gas mixture contains HBr, NO2, and C2H6 at STP.If a tiny hole is made in the container, which gas will effuse fastest?Which ga

s molecules have the highest average kinetic energy at this temperature?
Chemistry
1 answer:
MakcuM [25]2 years ago
5 0

Explanation:

Molar mass of HBr = 81 g/mol

Molar mass of nitrogen dioxide gas = 46 g/mol

Molar mass of ethane = 30 g/mol

Graham's Law states that the rate of effusion or diffusion of gas is inversely proportional to the square root of the molar mass of the gas. The equation given by this law follows the equation:

\text{Rate of diffusion}\propto \frac{1}{\sqrt{\text{Molar mass of the gas}}}

So, the gas with least molar mass will effuse out fastest from the container and that is ethane gas.

The formula for average kinetic energy is:

K.E=\frac{3}{2}kT

where,

k = Boltzmann’s constant = 1.38\times 10^{-23}J/K

T = temperature = 273.15 K ( at STP)

As we can see from the formula that kinetic energy depends upon only temperature of the gas molecule.

So, from this we can say that all the gas molecules have the same average kinetic energy at this temperature.

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Calculate the volume occupied by 10 kg of n-butane at 50 bar and 60°C using a) Ideal gas b) the Redlich-Kwong equation c) the ge
sladkih [1.3K]

Answer:

a. 95.35 L b. 20.52 L c. 19.07 L

Explanation:

Hello,

In the attached picture, you will find the solution for this exercise.

Take into account that for the Redllich-Kwong volume, a cubic polynomial must be solved to get the roots, thus, two roots are complex and one contains the molar volume which is converted to the volume I am showing.

In the following link you will find the corresponding states graph I used: https://www.slideserve.com/taipa/che-201-introduction-to-chemical-engineering

Best regards.

4 0
2 years ago
Consider the following chemical reaction: CO (g) + 2H2(g) ↔ CH3OH(g) At equilibrium in a particular experiment, the concentratio
AlexFokin [52]

Answer:

The equilibrium concentration of CH₃OH is 0.28 M

Explanation:

For the reaction: CO (g) + 2H₂(g) ↔ CH₃OH(g)

The equilibrium constant (Keq) is given for the following expresion:

Keq= \frac{(CH3OH)}{(CO) x (H2)^{2}} =14.5

Where (CH3OH), (CO) and (H2) are the molar concentrations of each product or reactant.

We have:

(CH3OH)= ?

(CO)= 0.15 M

(H2)= 0.36 M

So, we only have to replace the concentrations in the equilibrium constant expression to obtain the missing concentration we need:

14.5= \frac{(CH_{3}OH) }{(0.15 M) x (0.36 M) ^{2} }

14.5 x (0.15 M) x (0.36)^{2} = (CH₃OH)

0.2818 M = (CH₃OH)

6 0
2 years ago
A sample of neon effuses from a container in 72 seconds. the same amount of an unknown noble gas requires 147 seconds. you may w
Alexxx [7]
The   second gas  is  identified  as  follows

by  Graham law  formula
let  the  unknown gas  be  represented  by  letter y

=time of  effusion of Neon/ time  of effusion of  y =   sqrt (molar mass of neon/molar  mass of y)

= 72  sec/ 147  sec =  sqrt( 20.18  g/mol/ y   g/mol)

square the  both  side  to  remove  the  square  root  sign

72^2/147^2  = 20.18 g/mol/y g/mol

=0.24 = 20.18g/mol/y g/mol

multiply  both side  by  y  g/mol
= 0.24  y g/mol = 20.18g/mol
divide both side  by  0.24 
y =  84  g/mol

y  is  therefore Krypton  since  it  is  the one  with a molar mass  of  84 g/mol
6 0
2 years ago
Read 2 more answers
The three‑dimensional structure of a generic molecule is given. Identify the axial and equatorial atoms in the three‑dimensional
Dima020 [189]

Answer:

Explanation:

CHECK THE ATTACHMENT FOR THE COMPLETE QUESTION AND THE DETAILED EXPLANATION

NOTE:

Equatorial atoms are referred to atoms that are attached to carbons in the cyclohexane ring which is found at the equator of the ring.

Axial atoms are atoms that exist in a bond which is parallel to the axis of the ring in cyclohexane

4 0
2 years ago
For a particular reaction, ΔH∘=67.7 kJ/molΔH∘=67.7 kJ/mol and Δ????∘=126.9 J/(mol⋅K).ΔS∘=126.9 J/(mol⋅K). Assuming these values
Pavlova-9 [17]

Answer:

T=533.49\, K

For temperatures higher than 533.49 K we will see a spontaneous reaction, and for temperatures lower than that the reaction will not be spontaneous.

Explanation:

When are chemical reactions spontaneous? To find out we need to look at the reaction's change in Gibbs Free energy:

\Delta G=\Delta H-T\Delta S

When this is greater than zero, the reaction isn't spontaneous, when it is less than zero, we have a spontaneous reaction. The reaction must then change from spontaneous to non spontaneous when \Delta G=0. If we insert that into our equation we get:

0=\Delta H-T\Delta S\\\\T=\frac{\Delta H}{\Delta S}

That is the temperature at which the reaction's spontaneity will change, plugging in our values we find:

T=533.49\, K

At that temperature we have  \Delta G=0.

Now, at a temperature greater than this one, the entropy term in our equation for the Gibbs' free energy of reaction will take over, and make  \Delta G, thus the reaction will be spontaneous.

On the other hand, if we lower the temperature, we will have a smaller entropy term, and we will have:  \Delta G>0. That is, the reaction will not be spontaneous. Therefore for temperatures higher than 533.49 K we will see a spontaneous reaction, and for temperatures lower than that the reaction will not be spontaneous.

8 0
2 years ago
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