In given data:
maximum absorption wavelength λ = 580 nm = 580 x 10⁻⁹ m
write the equation to find the crystal field splitting energy:
E = hC / λ
Here, E is the crystal field splitting energy, h = 6.63 x 10⁻³⁴ J.sec is Planck's constant and C = 3 x 10⁸ m/sec is speed of light.
substitute in the equation above:
E = (6.64 x 10⁻³⁴ x 3 x 10⁸) / (580 x 10⁻⁹) = 3.43 x 10⁻¹⁹J
This crystal field splitting energy is for 1 ion.
Number of atoms in one mole, NA = 6.023 x 10²³
to calculate the crystal field splitting energy for one mole:
E(total) = E x NA
= (3.43 x 10⁻¹⁹) x (6.023 x 10²³) = 206 kJ/ mole
<span>A 50-gram sample with a half-life of 12 days will have a remaining mass of 25 grams after its 12-day half-life.
Every cycle of a half-life, the sample will lose half of its mass, so if the half-life, itself, is 12 days and the time period passing is 12 days, one half-life has passed and the material will be halved.</span>
Answer:
Atomic mass = 127.198 amu
Explanation:
The average atomic mass is obtained by summing the masses of the isotopes each multiplied by its abundance.
Atomic mass = (97.62 * 0.0825) + (109.3 * 0.2671) + (138.3 * 0.6504)
Atomic mass = 8.05365 + 29.19403 + 89.95032
Atomic mass = 127.198 amu
The reaction is:
4 PCl3 (g) ---> P4(s) + 6 Cl2(g).
Now, you need to convert the mass of PCl3 into number of moles, for which you use the molar mass of PCl3 in this way:
number of moles = number of grams / molar mass =>
number of moles of PCl3 = 612 g / 137.32 g/mol = 4.4567 moles of PCl3.
Now use the proportion with the ΔH rxn given.
4 mol PCl3 / 1207 kJ = 4.4567 mol / x => x = 4.4567 mol * 1207 kJ / 4 mol = 1,344.8 kJ = 1.34 * 10^3 kJ.
Answer: 1.34 * 10 ^3 kJ (option d)
<span>It takes 3 breaths to get to 1.2 l. One breath is then (1.2 l) / 3 breaths = .4l/breath.
To get to 3.0 l we need the difference from 1.2 l.
3.0-1.2 = 1.8 l.
Divide the difference by liters/breath (.4) to get how many needed breaths.
(1.8 l)/(.4 l/breath) = 4.5 breaths to get the balloon to 3.0 l.
In total there were 3 breaths+ 4.5 breaths = 7.5breaths to get to 3.0 l.
To find the total moles multiply 7.5breaths by .060 moles/breath
7.5 breaths*.060moles/breath = .45moles</span>
