Answer:
Maintaining a high starting-material concentration can render this reaction favorable.
Explanation:
A reaction is <em>favorable</em> when <em>ΔG < 0</em> (<em>exergonic</em>). ΔG depends on the temperature and on the reaction of reactants and products as established in the following expression:
ΔG = ΔG° + R.T.lnQ
where,
ΔG° is the standard Gibbs free energy
R is the ideal gas constant
T is the absolute temperature
Q is the reaction quotient
To make ΔG < 0 when ΔG° > 0 we need to make the term R.T.lnQ < 0. Since T is always positive we need lnQ to be negative, what happens when Q < 1. Q < 1 implies the concentration of reactants being greater than the concentration of products, that is, maintaining a high starting-material concentration will make Q < 1.
The reaction between boron sulfide and carbon is given as:
2B2S3 + 3C → 4B + 3CS2
As per the law of conservation of mass, for any chemical reaction the total mass of reactants must be equal to the total mass of the products.
Given data:
Mass of C = 2.1 * 10^ 4 g
Mass of B = 3.11*10^4 g
Mass of CS2 = 1.47*10^5
Mass of B2S3 = ?
Now based on the law of conservation of mass:
Mass of B2S3 + mass C = mass of B + mass of CS2
Mass of B2S3 + 2.1 * 10^ 4 = 3.11*10^4 + 1.47*10^5
Mass of B2S3 = 15.7 * 10^4 g
Answer:
203 grams
Explanation:
<em>It is known that 1.0 mole of a compound contains Avogadro's number of molecules (6.022 x 10²³).
</em>
<em><u>Using cross multiplication:</u></em>
1.0 mol contains → 6.022 x 10²³ molecules.
??? mol contains → 7.2 x 10²⁴ molecules.
∴ The no. of moles of (6.3 x 10²⁴ molecules) of NH₃ = (1.0 mol)(7.2 x 10²⁴ molecules)/(6.022 x 10²³ molecules) = 11.96 mol.
<em>∴ The no. of grams of NH₃ present = no. of moles x molar mass </em>= (11.96 mol)(17.0 g/mol) = <em>203.3 g ≅ 203.0 g.</em>
Answer : The correct option is, (a) paramagnetic with two unpaired electrons.
Explanation :
According to the molecular orbital theory, the general molecular orbital configuration will be,
![(\sigma_{1s}),(\sigma_{1s}^*),(\sigma_{2s}),(\sigma_{2s}^*),(\sigma_{2p_z}),[(\pi_{2p_x})=(\pi_{2p_y})],[(\pi_{2p_x}^*)=(\pi_{2p_y}^*)],(\sigma_{2p_z}^*)](https://tex.z-dn.net/?f=%28%5Csigma_%7B1s%7D%29%2C%28%5Csigma_%7B1s%7D%5E%2A%29%2C%28%5Csigma_%7B2s%7D%29%2C%28%5Csigma_%7B2s%7D%5E%2A%29%2C%28%5Csigma_%7B2p_z%7D%29%2C%5B%28%5Cpi_%7B2p_x%7D%29%3D%28%5Cpi_%7B2p_y%7D%29%5D%2C%5B%28%5Cpi_%7B2p_x%7D%5E%2A%29%3D%28%5Cpi_%7B2p_y%7D%5E%2A%29%5D%2C%28%5Csigma_%7B2p_z%7D%5E%2A%29)
As there are 14 electrons present in the given configuration.
The molecular orbital configuration of molecule will be,
![(\sigma_{1s})^2,(\sigma_{1s}^*)^2,(\sigma_{2s})^2,(\sigma_{2s}^*)^2,(\sigma_{2p_z})^2,[(\pi_{2p_x})^1=(\pi_{2p_y})^1],[(\pi_{2p_x}^*)^0=(\pi_{2p_y}^*)^0],(\sigma_{2p_z}^*)^0](https://tex.z-dn.net/?f=%28%5Csigma_%7B1s%7D%29%5E2%2C%28%5Csigma_%7B1s%7D%5E%2A%29%5E2%2C%28%5Csigma_%7B2s%7D%29%5E2%2C%28%5Csigma_%7B2s%7D%5E%2A%29%5E2%2C%28%5Csigma_%7B2p_z%7D%29%5E2%2C%5B%28%5Cpi_%7B2p_x%7D%29%5E1%3D%28%5Cpi_%7B2p_y%7D%29%5E1%5D%2C%5B%28%5Cpi_%7B2p_x%7D%5E%2A%29%5E0%3D%28%5Cpi_%7B2p_y%7D%5E%2A%29%5E0%5D%2C%28%5Csigma_%7B2p_z%7D%5E%2A%29%5E0)
The number of unpaired electron in the given configuration is, 2. So, this is paramagnetic. That means, more the number of unpaired electrons, more paramagnetic.
Hence, the correct option is, (a) paramagnetic with two unpaired electrons.
Specific heat capacity is the required amount of heat per unit of mass in order to raise teh temperature by one degree Celsius. It can be calculated from this equation: H = mCΔT where the H is heat required, m is mass of the substance, ΔT is the change in temperature, and C is the specific heat capacity.
H = m<span>CΔT
2501.0 = 0.158 (C) (61.0 - 32.0)
C = 545.8 J/kg</span>·°C
