An acid donates ion in aqueous solution. A base accepts
ion in aqueous solution.
The equation representing the acid base reaction of and
:
In the above reaction, as acts as a base it is accepting the hydrogen ion from
. Similarly,
donates its hydrogen ion to
acting as an acid.
Answer:
The pH of 0.1 M BH⁺ClO₄⁻ solution is <u>5.44</u>
Explanation:
Given: The base dissociation constant: = 1 × 10⁻⁴, Concentration of salt: BH⁺ClO₄⁻ = 0.1 M
Also, water dissociation constant: = 1 × 10⁻¹⁴
<em><u>The acid dissociation constant </u></em>()<em><u> for the weak acid (BH⁺) can be calculated by the equation:</u></em>
<em><u>Now, the acid dissociation reaction for the weak acid (BH⁺) and the initial concentration and concentration at equilibrium is given as:</u></em>
Reaction involved: BH⁺ + H₂O ⇌ B + H₃O+
Initial: 0.1 M x x
Change: -x +x +x
Equilibrium: 0.1 - x x x
<u>The acid dissociation constant: </u>
<u>Therefore, the concentration of hydrogen ion: x = 3.6 × 10⁻⁶ M</u>
Now, pH = - ㏒ [H⁺] = - ㏒ (3.6 × 10⁻⁶ M) = 5.44
<u>Therefore, the pH of 0.1 M BH⁺ClO₄⁻ solution is 5.44</u>
Explanation:
The given data is as follows.
Moles of propylene = 100 moles, = 300 K
= 800 K,
,
of propylene = 100 J/mol
Now, we assume the following assumptions:
Since, it is a compression process therefore, work will be done on the system. And, work done will be equal to the heat energy liberating without any friction.
W =
=
= 5 MJ
Thus, we can conclude that a minimum of 5 MJ work is required without any friction.