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hodyreva [135]
2 years ago
6

A sample of gas (1.9 mol) is in a flask at 21 °C and 697 mmHg. The flask is opened and more gas is added to the flask. The new p

ressure is 795 mmHg and the temperature is now 26 °C. There are now __________ mol of gas in the flask.
Chemistry
1 answer:
mariarad [96]2 years ago
4 0

Answer:

The new moles of the gas in the flask is 2.13 moles.

Explanation:

Given;

number of moles of gas, n = 1.9 mol

temperature of the gas, T = 21 °C  = 21 + 273 = 294 K

pressure of gas, P = 697 mmHg

volume of gas, V = ?

Apply ideal gas law;

PV = nRT

Where;

R is gas constant, = 62.363 mmHg.L / mol. K

V = nRT / P

V = (1.9 x 62.363 x 294) / 697

V = 49.98 L

New pressure of the gas, P = 795 mmHg

New temperature of the gas, T = 26 °C = 273 + 26 = 299 K

New moles of the gas, n = ?

Volume of the gas is constant because volume of the flask is the same when more gas was added.

n = PV / RT

n = (795 x 49.98) / (62.363 x 299)

n = 2.13 moles

Therefore, the new moles of the gas in the flask is 2.13 moles.

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Describe how you would prepare exactly 100 mL of 0.109 M picolinate buffer, pH 5.61. Possible starting materials are pure picoli
Pepsi [2]

Answer:

1.342g of picolinic acid and 6.743mL of 1.0M NaOH diluting the mixture to 100.0mL

Explanation:

<em>The pKa of the picolinic acid is 5.4.</em>

Using Henderson-Hasselbalch formula for picolinic-picolinate buffer:

pH = pKa + log [Picolinate] / [Picolinic]

<em>Where [] could be taken as moles of each species</em>

<em />

5.61 = 5.4 + log [Picolinate] / [Picolinic]

0.21 = log [Picolinate] / [Picolinic]

1.62181 = [Picolinate] / [Picolinic] <em>(1)</em>

<em></em>

Now, both picolinate and picolinic acid will be:

0.100L * (0.109mol / L) =

0.0109 moles = [Picolinate] + [Picolinic] <em>(2)</em>

<em></em>

First, as we will start with picolinic acid, we need add:

0.0109 moles picolinic acid * (123.10g/mol) = 1.342g of picolinic acid

Now, replacing (2) in (1):

1.62181 = 0.0109 moles - [Picolinic] / [Picolinic]

1.62181 [Picolinic] = 0.0109 moles - [Picolinic]

2.62181 [Picolinic] = 0.0109 moles

[Picolinic] = 4.157x10⁻³ moles

And:

[Picolinate] = 0.0109 - 4.157x10⁻³ moles =

<h3>6.743x10⁻³ moles</h3><h3 />

To obtain these moles of picolinate ion we need to make the reaction of the picolinic acid with NaOH:

Picolinic acid + NaOH → Picolinate + Water

<em>That means to obtain 6.743x10⁻³ moles of picolinate ion we need to add 6.743x10⁻³ moles of NaOH</em>

<em />

6.743x10⁻³ moles of NaOH that is 1.0M are, in mL:

6.743x10⁻³ moles * (1L / 1mol) = 6.743x10⁻³L * 1000 =

<h3>6.743mL of the 1.0M NaOH must be added</h3><h3 />

Thus, we obtain the desire moles of picolinate and picolinic acid to obtain the buffer we want, the last step is:

<h3>Dilute the mixture to 100mL, the volume we need to prepare</h3>
3 0
2 years ago
The pH of an aqueous solution is 4.32. What is the [OH–]?
Molodets [167]
2.10 x 10^-10 M. Ans


pH + pOH = 14
Where, pOH is the power of hydroxide ion concentration and pH is the power of concetration of the H+ ion.
Now, pOH = 14 - 4.32
= 9.68
Now, the concentration of [H+] is 10-7 M, then pH is 7 and for [OH-] = 10-7 M, the pOH is also 7.

Now, pOH = -log[OH-]
[OH-] = 10^- pOH
= 10^-9.68
= 2.10 x 10^-10 M

8 0
2 years ago
The solubility of KCl is 3.7 M at 20 °C. Two beakers each contain 100. mL of saturated KCl solution: 100. mL of 4.0 M HCl is add
JulijaS [17]

Answer:

a)The Ksp was found to be equal to 13.69

Explanation:

Terminology

Qsp of a dissolving ionic solid — is the solubility product of the concentration of ions in solution.

Ksp however, is the solubility product of the concentration of ions in solution at EQUILIBRIUM with the dissolving ionic solid.

Note that if Qsp > Ksp , the solid at a certain temperature, will precipitate and form solid. That means the equilibrium will shift to the left in order to attain or reach equilibrium (Ksp).

Step-by-step solution:

To solve this: 

#./ Substitute the molar solubility of KCl as given into the ion-product equation to find the Ksp of KCl.

#./ Find the total concentration of ionic chloride in each beaker after the addition of HCl. We pay attention to the amount moles present at the beginning and the moles added.

#./ Find the Qsp value to to know if Ksp is exceeded. If Qsp < Ksp, nothing will precipitate.

a) The equation of solubility equilibrium for KCL is thus;

KCL_(s) ---> K+(aq) + Cl- (aq)

The solubility of KCl given is 3.7 M.

Ksp= [K+][Cl-] = (3.7)(3.7) =13.69

The Ksp was found to be equal to 14.

In pure water KCl

Ksp =13.69 KCl =[K+][Cl-]

Let x= molar solubility [K+],/[Cl-] :. × , x

Ksp =13.69 = [K+][Cl-] = (x)(x) = x²

x= √ 13.69 = 3.7 M moles of KCl requires to make 100mL saturated solutio

37M moles/L

The Ksp was found to be equal to 14.

4.0 M HCl = KCl =[K+][Cl-]

Let y= molar solubility :. y, y+4

Ksp =13.69= [K+][Cl-] = (y)(y*+4)

* - rule of thumb

Ksp =13.69= [K+][Cl-] = (y)(y*+4)= y(4)

13.69=4y:. y= 3.42 moles/100mL

y= 34.2moles/L

8 M HCl = KCl =[K+][Cl-]

Let b= molar solubility :. B, b+8

Ksp =13.69= [K+][Cl-] = (b)(b*+8)

* - rule of thumb

Ksp =13.69= [K+][Cl-] = (b)(b*+8)= b(8)

13.69=8b:. b= 1.71 moles/100mL

17.1 moles/L

Therefore in a solution with a common ion, the solubility of the compound reduces dramatically.

8 0
2 years ago
Read 2 more answers
Rank the formation of the solutions A, B, and C from the most exothermic to the most endothermic. Rank the enthalpy of solution
Elodia [21]

This is an incomplete question, the table is attached below.

Answer : The correct ranking of the solution from most exothermic to most endothermic will be: A, B and C.

Explanation :

As we know that the intermolecular force of attraction play an important role in the interaction of solute-solute, solute-solvent and solvent solvent solution.

In the solution A, the solute-solute and solvent-solvent interactions are weak. So, their solute-solvent interaction will be strong. That means, the solution will be more exothermic.

In the solution C, the solute-solute and solvent-solvent interactions are strong. So, their solute-solvent interaction will be weak. That means, the solution will be more endothermic.

Thus, the correct ranking of the solution from most exothermic to most endothermic will be: A, B and C.

4 0
2 years ago
1. Which liquid sample is a pure substance?
IRISSAK [1]

The whole Activity , poem and paragraph is missing in the question.

Answer:

(1) Liquid A

(2) Solid A

Explanation:

Using this part of the given poem

Substances and mixtures behave differently,

During boiling and melting most especially

Boiling point of substance is fixed while mixture is not

Substance melts completely but mixture does not

The boiling point of the Pure substance remain fixed after reaching its boiling point this is shown by Liquid A

Solid A is melting completely so Solid A is a pure substance.

6 0
2 years ago
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