0.6137 g of KHP contains 1.086 × 10^21 acidic protons.
Number of moles of KHP = mass of KHP/molar mass of KHP
Molar mass of KHP = 204.22 g/mol
Mass of KHP = 0.6137 g
Number of moles of KHP = 0.6137 g/204.22 g/mol = 0.003 moles of KHP
Now, 1 each molecule of KHP contains 1 acidic proton.
For 0.003 moles of KHP there are; 0.003 × 1 × NA
Where NA is Avogadro's number.
So; 0.003 moles of KHP contains 0.003 × 1 × 6.02 × 10^23
= 1.086 × 10^21 acidic protons.
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In buffer solution there is an equilibrium between the acid HA and its conjugate base A⁻: HA(aq) ⇌ H⁺(aq) + A⁻(aq).
When acid (H⁺ ions) is added to the buffer solution, the equilibrium is shifted to the left, because conjugate base (A⁻) reacts with hydrogen cations from added acid, according to Le Chatelier's principle: H⁺(aq) + A⁻(aq) ⇄ HA(aq). So, the conjugate base (A⁻) consumes some hydrogen cations and pH is not decreasing (less H⁺ ions, higher pH of solution).
A buffer can be defined as a substance that prevents the pH of a solution from changing by either releasing or absorbing H⁺ in a solution.
Buffer is a solution that can resist pH change upon the addition of an acidic or basic components and it is able to neutralize small amounts of added acid or base, pH of the solution is relatively stable
Answer:
The possible structures are ketone and aldehyde.
Explanation:
Number of double bonds of the given compound is calculated using the below formula.

=Number of double bonds
= Number of carbon atoms
= Number of hydrogen atoms
= Number of nitrogen atoms
The number of double bonds in the given formula - 

The number of double bonds in the compound is one.
Therefore, probable structures is as follows.
(In attachment)
The structures I and III are ruled out from the probable structures because the signal in 13C-NMR appears at greater than 160 ppm.
alkene compounds I and II shows signal less than 140 ppm.
Hence, the probable structures III and IV are given as follows.
The carbonyl of structure I appear at 202 and ketone group of IV appears at 208 in 13C, which are greater than 160.
Hence, the molecular formula of the compound
having possible structure in which the signal appears at greater than 160 ppm are shown aw follows.
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