Answer: All of the statements are true.
Explanation:
(a) Considering the system mentioned in the equation:-
The sum of total moles in the flask will always be equal to 1 which leads to confirmation of this statement as for 60 secs= 0.16 mol A and 0.84 mol B
(b) 0<t< 20s, mole A got reduced from 1 mole to 0.54 moles while at 40s to 60s A got decreased from 0.30 moles to 0.16 moles.
0 to 20s is 0.46 (1 - 0.54 = 0.46)mol whereas,
40 to 60s is 0.14 (0.30-.16 = 0.14) mol
(0.46 > 0.14) mol leading this statement to be true as well.
(c) Average rate from t1 = 40 to t2 = 60 s is given by:
which is true as well
Answer:
The partial pressure of neon in the vessel was 239 torr.
Explanation:
In all cases involving gas mixtures, the total gas pressure is related to the partial pressures, that is, the pressures of the individual gaseous components of the mixture. Put simply, the partial pressure of a gas is the pressure it exerts on a mixture of gases.
Dalton's law states that the total pressure of a mixture of gases is equal to the sum of the pressures that each gas would exert if it were alone. Then:
PT= P1 + P2 + P3 + P4…+ Pn
where n is the amount of gases present in the mixture.
In this case:
PT=PN₂ + PAr + PHe + PNe
where:
- PT= 987 torr
- PN₂= 44 torr
- PAr= 486 torr
- PHe= 218 torr
- PNe= ?
Replacing:
987 torr= 44 torr + 486 torr + 218 torr + PNe
Solving:
987 torr= 748 torr + PNe
PNe= 987 torr - 748 torr
PNe= 239 torr
<u><em>The partial pressure of neon in the vessel was 239 torr.</em></u>
Given reaction represents dissociation of bromine gas to form bromine atoms
Br2(g) ↔ 2Br(g)
The enthalpy of the above reaction is given as:
ΔH = ∑n(products)Δ
- ∑n(reactants)Δ
where n = number of moles
Δ
= enthalpy of formation
ΔH = [2*ΔH(Br(g)) - ΔH(Br2(g))] = 2*111.9 - 30.9 = 192.9 kJ/mol
Thus, enthalpy of dissociation is the bond energy of Br-Br = 192.9 kJ/mol
