What volume will 6.745g of neon gas occupy at standard temp and pressure?
2 answers:
Explanation:
It is given that mass of neon is 6.745 g and molar mass of neon is 20 g/mol.
Hence, calculate the number of moles as follows.
No. of moles =
Putting the given values into the above formula as follows.
No. of moles =
=
= 0.34 mol
Also, at standard conditions value of temperature is 298 K and pressure is 1 atm.
So, putting the values into ideal gas equation and calculate the value of volume as follows.
PV = nRT
V = 8.31 L
Thus, we can conclude that volume of given neon gas is 8.31 L.
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Answer:
Less than the concentration of Pb2+(aq) in the solution in part ( a )
Explanation:
From the question:
A)
We assume that s to be the solubility of PbI₂.
The equation of the reaction is given as :
PbI₂(s) ⇌ Pb²⁺(aq) + 2I⁻(aq); Ksp = 7 × 10⁻⁹
[Pb²⁺] = s
Then [I⁻] = 2s
B)
The Concentration of Pb²⁺ in water is calculated as :
The Concentration of Pb²⁺ in 1.0 mol·L⁻¹ NaI
The equilibrium constant:
It is now clear that maximum possible concentration of Pb²⁺ in the solution is less than that in the solution in part (A). This happens due to the common ion effect. The added iodide ion forces the position of equilibrium to shift to the left, reducing the concentration of Pb²⁺.
The structures of the isomers and the m/z values of their peaks are not given in the question. The complete question is provided in the attachment
Answer:
Compound 2 (2,5-dimethylhexane) will not have the peaks at 29 and 85 m/z
Explanation:
The fragmentation of molecules by electron ionization of mass spectrometer occurs according to Stevenson's Rule, which states that "The most probable fragmentation is the one that leaves the positive charge on the fragment with the lowest ionization energy". This is much like the Markovnikov's Rule in organic chemistry which has predicted the formation of most stable carbocation and the addition of hydrogen halide to it.
The mass spectra of compound 1 (2,4-dimethylhexane) will contain all the m/z values mentioned in the question. Each peak indicate towards homologous series of fragmentation product of the compound 1. The first peak can be attributed to ethyl carbocation (m/z = 29), with the increase of 14 units the next peak indicates towards propyl carbocation (m/z = 43) and onwards until molecular ion peak of 114 m/z.
Compound 2 (2,5-dimethylhexane) structure shows that the cleavage of C-C bond will not yield a stable ethyl and hexyl carbocation. Hence, no peaks will be observed at 29 and 85 m/z. The absence of these two peaks can be used to distinguish one isomer from the other.
