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frez [133]
2 years ago
3

Calculate whether a precipitate will form (and why) if 0.35 l of 0.0044 m ca(no3)2 and 0.17 l of 0.00039 m naoh are mixed at 25◦

c. ksp for ca(oh)2 is equal to 5.5 × 10−6.
Chemistry
1 answer:
VashaNatasha [74]2 years ago
3 0
Chemical reaction: Ca(NO₃)₂ + 2NaOH → Ca(OH)₂ + 2NaNO₃.
c₁(Ca(NO₃)₂) · V₁(Ca(NO₃)₂) = c₂(Ca(NO₃)₂) · V₂(Ca(NO₃)₂).
0.0044 M · 0.35 L = c₂(Ca(NO₃)₂) · (0.35 L + 0.17 L).
[Ca²⁺] = c₂(Ca(NO₃)₂) = 0.00296 M.
c₁(NaOH) · V₁(NaOH) = c₂(NaOH) · V₂(NaOH).
0.00039 M · 0.17 L = c₂(NaOH) · (0.35 L + 0.17 L)
[OH⁻] = c₂(NaOH) = 0.0001275 M.
Q(Ca(OH)₂) = [Ca²⁺] · [OH⁻]².
Q = 0.00296 M · (0.0001275 M)² = 4.9·10⁻¹¹.
Ca(OH)₂ does not precipitate because <span>Q < Ksp.</span>

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puteri [66]

<u>Answer:</u>

<u>For a:</u> The equilibrium mixture contains primarily reactants.

<u>For b:</u> The equilibrium mixture contains primarily products.

<u>Explanation:</u>

There are 3 conditions:

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For the given chemical reactions:

  • <u>For a:</u>

The chemical equation follows:

HCN(aq.)+H_2O(l)\rightleftharpoons CN^-(aq.)+H_3O^+(aq.);K_{eq}=6.2\times 10^{-10}

The expression of K_{eq} for above reaction follows:

K_{eq}=\frac{[CN^-][H_3O^+]}{[HCN][H_2O]}=6.2\times 10^{-10}

As, K_{eq}, the reaction will be favored on the reactant side.

Hence, the equilibrium mixture contains primarily reactants.

  • <u>For b:</u>

The chemical equation follows:

H_2(g)+Cl_2(g)\rightleftharpoons 2HCl(g);K_{eq}=2.51\times 10^{4}

The expression of K_{eq} for above reaction follows:

K_{eq}=\frac{[HCl]^2}{[H_2][Cl_2]}=2.51\times 10^{4}

As, K_{eq}>1, the reaction will be favored on the product side.

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Answer:

A

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In an octahedral crystal field, there are two sets of degenerate orbitals; the lower lying three t2g orbitals, and the higher level two degenerate eg orbitals. Strong field ligands cause high octahedral crystal field splitting, there by separating the two sets of degenerate orbitals by a tremendous amount of energy. This energy is much greater than the pairing energy required to pair the six electrons in three degenerate orbitals. Since CN- is a strong field ligand, it leads to pairing of six electrons in three degenerate orbitals

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