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ollegr [7]
2 years ago
6

Given that the density of TlCl(s) is 7.00 g/cm3 and that the length of an edge of a unit cell is 385 pm, determine how many form

ula units of TlCl there are in a unit cell.
Chemistry
1 answer:
ryzh [129]2 years ago
3 0
Here's my best guess
the volume of the unit cell is (385*10^-12)^3=5.7066*10^-29 m^3
multiply by density to get mass mass = (7 g/cm^3)*(100^3 cm^3 / 1^3 m^3) * 5.7066*10^-29 m^3= 3.99466*10^-22 g
covert to moles 3.99466*10^-22 g * 1 mol / 239.82 g = 1.6657 *10^-24 mol
convert to number of units

1.6657 *10^-24 mol * 6.23*10^23 units/mol = 1.04

385 pm = 3.85*10^(-8) cm

The volume of the unit cell is the cube of that, which is 5.71*10^(-23) cm^3. Since the ratio of mass to volume (i.e. the density) must be the same no matter what amount of TlCl you have, you can say:
7 = x/(5.71*10^(-23)), where x is the mass of the unit cell. Solving for x, you get 4*10^(-22) g.

The mass of a molecule of TlCl is 240 amu, which in grams is 4*10^(-22) g. The mass of the unit cell and the mass of a molecule of TlCl is the same. Therefore there is one formula unit of TlCl per unit cell.

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4 0
2 years ago
Read 2 more answers
The activation energy for the reaction no2(g)+co(g)⟶no(g)+co2(g) is ea = 75 kj/mol and the change in enthalpy for the reaction i
Nonamiya [84]
Answer: 350 kj/mol


Explanation:

As shown below this expression gives the activation energy of the reverse reaction:

EA reverse reaction = EA forward reaction + | enthalpy change |

1) The activation energy, EA is the difference between the potential energies of the reactants and the transition state:

EA = energy of the transition state - energy of the reactants.

2) The activation energy of the forward reaction given is:

EA = energy of the transition state - energy of  [ NO2(g) + CO(g) ] = 75 kj/mol

3) The negative enthalpy change - 275 kj / mol for the forward reaction means that the products are below in the potential energy diagram, and that the potential energy of the products, [NO(g) + CO2(g) ] is equal to 75 kj / mol - 275 kj / mol = - 200 kj/mol

4) For the reverse reaction the reactants are [NO(g) + CO2(g)], and the transition state is the same than that for the forward reaction.

5) The difference of energy between the transition state and the potential energy of [NO(g) + CO2(g) ] will be the absolute value of the change of enthalpy plus the activation energy for the forward reaction:

EA reverse reaction = EA forward reaction + | enthalpy change |

EA reverse reaction = 75 kj / mol + |-275 kj/mol | = 75 kj/mol + 275 kj/mol = 350 kj/mol.

And that is the answer, 350 kj/mol

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Answer:

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Explanation:

Recall that group 5A elements contain five electrons in their outermost shell. These five electrons consists of a lone pair and three electrons that can form three bonds with hydrogen to give YH3 where Y is the group 5A element.

The YH3 molecule contains one lone(unshared) pair of electrons as well as three bonding pairs of electrons. The compounds are covalent.

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