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Fiesta28 [93]
2 years ago
8

Identify the conjugate acid base pair H3PO4(ag)+CO32=HCO3-(ag)+HPO42-(ag)

Chemistry
1 answer:
viktelen [127]2 years ago
3 0

Answer:

H₃PO₄/H₂PO₄⁻ and HCO₃⁻/CO₃²⁻

Explanation:

An acid is a proton donor; a base is a proton acceptor.

Thus, H₃PO₄ is the acid, because it donates a proton to the carbonate ion.

CO₃²⁻ is the base, because it accepts a proton from the phosphoric acid.

The conjugate base is what's left after the acid has given up its proton.

The conjugate acid is what's formed when the base has accepted a proton.

H₃PO₄/H₂PO₄⁻ make one conjugate acid/base pair, and HCO₃⁻/CO₃²⁻ are the other conjugate acid/base pair.

H₃PO₄ + CO₃²⁻ ⇌ H₂PO₄⁻ + HCO₃⁻

acid       base         conj.       conj.

                               base       acid

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Answer : The value of K_{eq} is, 11.2

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The relation between the equilibrium constant and standard Gibbs free energy is:

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where,

\Delta G^o = standard Gibbs free energy  = -5.980 kJ/mol = -5980 J/mol

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T = temperature = 25^oC=273+25=298K

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Now put all the given values in the above formula, we get:

\Delta G^o=-RT\times \ln K_{eq}

-5980J/mol=-(8.314J/K.mol)\times (298K)\times \ln K_{eq}

K_{eq}=11.2

Thus, the value of K_{eq} is, 11.2

Now we have to calculate the \Delta G_{rxn}.

The formula used for \Delta G_{rxn} is:

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A(aq)\rightleftharpoons B(aq)

\Delta G_{rxn}=\Delta G^o+RT\ln Q

\Delta G_{rxn}=\Delta G^o+RT\ln \frac{[B]}{[A]}    ............(1)

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\Delta G_{rxn} = Gibbs free energy for the reaction  = ?

\Delta G_^o =  standard Gibbs free energy  = -30.5 kJ/mol

R = gas constant = 8.314\times 10^{-3}kJ/mole.K

T = temperature = 37.0^oC=273+37.0=310K

Q = reaction quotient

[A] = concentration of A = 1.8 M

[B] = concentration of B = 0.55 M

Now put all the given values in the above formula 1, we get:

\Delta G_{rxn}=(-5980J/mol)+[(8.314J/mole.K)\times (310K)\times \ln (\frac{0.55}{1.8})

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Therefore, the value of \Delta G_{rxn} is -9.04 kJ/mol

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