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konstantin123 [22]
2 years ago
9

Calculate the mass of oxygen (in mg) dissolved in a 5.00 L bucket of water exposed to a pressure of 1.13 atm of air. Assume the

mole fraction of oxygen in air to be 0.21 and the Henry's law constant for oxygen in water at this temperature to be 1.3 x 10-3 M/atm. Group of answer choices
Chemistry
1 answer:
AleksAgata [21]2 years ago
6 0

Answer:

50 mg

Explanation:

First, we have to calculate the partial pressure of O₂ (pO₂) using the following expression.

pO₂ = P × X(O₂) = 1.13 atm × 0.21 = 0.24 atm

where,

P: total pressure

X(O₂): mole fraction of oxygen

Then, we can calculate the concentration of O₂ in water (C) using Henry's law.

C = k × pO₂ = (1.3 × 10⁻³ M/atm) × 0.24 atm = 3.1 × 10⁻⁴ M

where,

k: Henry's constant for O₂

The mass of oxygen in a 5.00 L bucket with a concentration of 3.1 × 10⁻⁴ M is: (MM 32.0 g/mol)

5.00L.\frac{3.1 \times 10^{-4}mol}{L} .\frac{32.0 \times 10^{3}mg}{mol} =50mg

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kifflom [539]

Answer : The equilibrium SO_2 pressure is, 3.93\times 10^{-5}torr

Explanation :

The given balanced chemical reaction is,

SO_2(g)+2H_2S(g)\rightleftharpoons 3S(s)+2H_2O(g)

First we have to calculate the standard free energy of reaction (\Delta G^o).

\Delta G^o=G_f_{product}-G_f_{reactant}

\Delta G^o=[n_{S(s)}\times \Delta G_f^0_{(S(s))}+n_{H_2O(g)}\times \Delta G_f^0_{(H_2O(g))}]-[n_{SO_2(g)}\times \Delta G_f^0_{(SO_2(g))}+n_{H_2S(g)}\times \Delta G_f^0_{(H_2S(g))}]

where,

\Delta G^o = standard free energy of reaction = ?

n = number of moles

Now put all the given values in this expression, we get:

\Delta G^o=[3mole\times (0kJ/mol)+2mole\times (-228.57kJ/mol)]-[1mole\times (-300.4kJ/mol)+2mole\times (-33.01kJ/mol)]

\Delta G^o=-90.72kJ/mol

Now we have to calculate the value of K_p

\Delta G^o=-RT\ln K_p

where,

\Delta G_^o =  standard Gibbs free energy  = -90.72 kJ/mol

R = gas constant = 8.314 J/mole.K

T = temperature = 298 K

K_p = equilibrium constant  = ?

Now put all the given values in this expression, we get:

-90.72kJ/mol=-(8.314J/mol.K)\times (298K) \ln K_p

K_p=7.98\times 10^{15}

Now we have to calculate the value of K_p.

The given balanced chemical reaction is,

SO_2(g)+2H_2S(g)\rightleftharpoons 3S(s)+2H_2O(g)

The expression for equilibrium constant will be :

K_p=\frac{(p_{H_2O})^2}{(p_{H_2S})^2\times (p_{SO_2})}

In this expression, only gaseous or aqueous states are includes and pure liquid or solid states are omitted.

Let the equilibrium SO_2 pressure be, x

Pressure of SO_2 = Pressure of H_2S = x

Now put all the given values in this expression, we get

7.98\times 10^{15}=\frac{(22)^2}{(x)^2\times (x)}

x=3.93\times 10^{-5}torr

Thus, the equilibrium SO_2 pressure is, 3.93\times 10^{-5}torr

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2 years ago
The four rows of data below show the boiling points for a solution with no solute, sucrose (C12H22O11), sodium chloride (NaCl),
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Answer:

The four rows of data below show the boiling points for a solution with no solute, sucrose (C12H22O11), sodium chloride (NaCl), and calcium chloride (CaCl2) (not in that order). Which boiling point corresponds to calcium chloride?

A. 101.53° C

B. 100.00° C

C. 101.02° C

D. 100.51° C

Which of the following solutions will have the lowest freezing point?

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B. 1.0 mol/kg lithium chloride (LiCl)

C. 1.0 mol/kg sodium phosphide (Na3P)

D. 1.0 mol/kg magnesium fluoride (MgF2)

Which of the following compounds will be most effective in melting the ice on the roads when the air temperature is below zero?

A. sodium iodide (NaI)

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D. All will be equally effective.

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A. 98.7 kPa

B. 96.3 kPa

C. 101.3 kPa

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Four different solutions have the following boiling points. Which boiling point corresponds to a solution with the lowest freezing point?

A. 101.2°C

B. 105.9°C

C. 102.7°C

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Explanation:

The following are the answers to the different questions: 

The four rows of data below show the boiling points for a solution with no solute, sucrose (C12H22O11), sodium chloride (NaCl), and calcium chloride (CaCl2) (not in that order). Which boiling point corresponds to calcium chloride?

A. 101.53° C

Which of the following solutions will have the lowest freezing point?

D. 1.0 mol/kg magnesium fluoride (MgF2)

Which of the following compounds will be most effective in melting the ice on the roads when the air temperature is below zero?

A. sodium iodide (NaI)

Four different solutions have the following vapor pressures at 100°C. Which solution will have the greatest boiling point?

B. 96.3 kPa

Four different solutions have the following boiling points. Which boiling point corresponds to a solution with the lowest freezing point?

D. 108.1°C

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2 years ago
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tamaranim1 [39]

Answer:

1.The diagram is attached

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