SThe missing coefficient for the skeleton equation below is as follows
skeleton equation
Cr(s) + Fe(No3)2(aq) ------> Fe (s) + Cr(NO3)3 (aq)
the missing coefficient are is as follows
2 Cr(s) + 3 Fe(NO3)2 ---> 3 Fe (s) + 2 Cr(NO3)3
This is obtained by making sure all the molecules are balanced in both sides
Given reaction represents dissociation of bromine gas to form bromine atoms
Br2(g) ↔ 2Br(g)
The enthalpy of the above reaction is given as:
ΔH = ∑n(products)Δ
- ∑n(reactants)Δ
where n = number of moles
Δ
= enthalpy of formation
ΔH = [2*ΔH(Br(g)) - ΔH(Br2(g))] = 2*111.9 - 30.9 = 192.9 kJ/mol
Thus, enthalpy of dissociation is the bond energy of Br-Br = 192.9 kJ/mol
Answer 1:
Equilibrium constant (K) mathematically expressed as the ratio of the concentration of products to concentration of reactant. In case of gaseous system, partial pressure is used, instead to concentration.
In present case, following reaction is involved:
2NO2 ↔ 2NO + O2
Here, K =
![\frac{[PNO]^2[O2]}{[PNO2]^2}](https://tex.z-dn.net/?f=%20%5Cfrac%7B%5BPNO%5D%5E2%5BO2%5D%7D%7B%5BPNO2%5D%5E2%7D%20)
Given: At equilibrium, <span>PNO2= 0.247 atm, PNO = 0.0022atm, and PO2 = 0.0011 atm
</span>
Hence, K =
![\frac{[0.0022]^2[0.0011]}{[0.247]^2}](https://tex.z-dn.net/?f=%20%5Cfrac%7B%5B0.0022%5D%5E2%5B0.0011%5D%7D%7B%5B0.247%5D%5E2%7D%20)
= 8.727 X 10^-8
Thus, equilibrium constant of reaction = 8.727 X 10^-8
.......................................................................................................................
Answer 2:
Given: <span>PNO2= 0.192 atm, PNO = 0.021 atm, and PO2 = 0.037 atm.
Therefore, Reaction quotient = </span>
![\frac{[PNO]^2[O2]}{[PNO2]^2}](https://tex.z-dn.net/?f=%20%5Cfrac%7B%5BPNO%5D%5E2%5BO2%5D%7D%7B%5BPNO2%5D%5E2%7D%20)
=
![\frac{[0.021]^2[0.037]}{[0.192]^2}](https://tex.z-dn.net/?f=%20%5Cfrac%7B%5B0.021%5D%5E2%5B0.037%5D%7D%7B%5B0.192%5D%5E2%7D%20)
= 4.426 X 10^-4.
Here, Reaction quotient > Equilibrium constant.
Hence, <span>the reaction need to go to
reverse direction to reattain equilibrium </span>
The more numbers after the decimal point there are, the more precise the instrument which recorded it is. For example, if one instrument during seismic activity records that the magnitude of the earthquake was 2.3, and another instrument recorded that it was 2.3645, the second instrument would have shown to be more precise.