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Natalija [7]
2 years ago
7

When determining the standard reduction potential of a substance by using a standard hydrogen electrode as a reference, the stan

dard reduction potential will always be equal to:______.
ta. he reduction potential for the standard hydrogen electrode.
b. one-half the cell potential.
c. the overall cell potential.
d. impossible to predict.
Chemistry
1 answer:
nika2105 [10]2 years ago
4 0

Answer:

the overall cell potential

Explanation:

We must bear in mind that the standard hydrogen electrode is a reference electrode whose electrode potential has been arbitrarily set at 0 V.

The standard hydrogen electrode consists of hydrogen ion solution and hydrogen gas together with a platinum electrode.

The overall cell potential is the reduction potential of the substance being determined using the standard hydrogen electrode as a reference electrode since its electrode potential is set at zero volts.

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A 5 mole sample of liquid acetone is converted to a gas at 75.0°C. If 628 J are required to raise the temperature of the liquid
Shkiper50 [21]
The total energy can be found by adding the different energies:
628 + 15,600 + 712
= 16.94 kJ
4 0
2 years ago
Calculate the cell potential E at 25°C for the reaction 2 Al(s) + 3 Fe2+(aq) → 2 Al3+(aq) + 3 Fe(s) given that [Fe 2+] = 0.020 M
Elodia [21]

Answer:

1.18 V

Explanation:

The given cell is:

Al(s)/Al^{3+}(0.10M)||Fe^{2+}(0.020M)/Fe(s)

Half reactions for the given cell follows:

Oxidation half reaction: Al(s)\rightarrow Al^{3+}(0.10M)+2e^-;E^o_{Al^{3+}/Al}=-1.66V

Reduction half reaction: Fe^{2+}(0.020M)+2e^-\rightarrow Fe(s);E^o_{Fe^{2+}/Fe}=-0.45V

Multiply Oxidation half reaction by 2 and Reduction half reaction by 3

Net reaction: 2Al(s)+3Fe^{2+}(0.020M)\rightarrow 2Al^{3+}(0.10M)+3Fe(s)

Oxidation reaction occurs at anode and reduction reaction occurs at cathode.

To calculate the E^o_{cell} of the reaction, we use the equation:

E^o_{cell}=E^o_{cathode}-E^o_{anode}

Putting values in above equation, we get:

E^o_{cell}=-0.45-(-1.66)=1.21V

To calculate the EMF of the cell, we use the Nernst equation, which is:

E_{cell}=E^o_{cell}-\frac{0.059}{n}\log \frac{[Al^{3+}]^2}{[Fe^{2+}]^3}

where,

E_{cell} = electrode potential of the cell = ?V

E^o_{cell} = standard electrode potential of the cell = +1.21 V

n = number of electrons exchanged = 6

Putting values in above equation, we get:

E_{cell}=1.21-\frac{0.059}{6}\times \log(\frac{0.10^2}{0.020^3})\\\\E_{cell}=1.18V

5 0
2 years ago
For the Bradford assay, the instructor will make a Bradford reagent dye by mixing 50 ml of 95% v/v ethanol with 100 mg of Coomas
jolli1 [7]

Answer:

4,25% v/v H3PO4

Explanation:

The concentration of phosphoric acid (H3PO4) is expressed as a volume / volume percentage, which means:

%v/v H3PO4 = (mL of pure H3PO4/mL of solution)*100%

In other words, <u>we are only interested in the final volume of the solution to which the phosphoric acid was diluted, regardless of its composition</u>. Which in this case is 1 L (1000 mL).

We can then apply the following equation, commonly used to calculate the initial or final concentration (or volume) of a substance when it is diluted:

Ci*Vi=Cf*Vf

<u>Where</u>:

Ci, is the initial concentration of the substance.

Vi, the initial volume of the substance

Cf, the final concentration reached after dilution

Vf, the final volume of the solution at which the substance was diluted

In this case, the incognite would be the final concentration of H3PO4 reached after dilution, that is, Cf. Therefore, we proceed to clear Cf from the previous equation and replace our data:

Cf = (Ci*Vi)/Vf = (85% v/v * 50 mL)/1000 mL = 4,25 % v/v

Note that being up and down in the division, the mL unit is canceled to result in% v / v.

7 0
2 years ago
If a penny is made of 3.11 grams of copper, how many atoms of copper are in the penny
Pie

Answer:

2.94x10²² atoms of Cu

Explanation:

We must work with NA to solve this, where NA is the number of Avogadro, number of particles of 1 mol of anything.

Molar mass Cu = 63.55 g/mol

Mass / Molar mass = Mol → 3.11 g / 63.55 g/m = 0.0489 moles

1 mol  of Cu has 6.02x10²³ atoms of Cu

0.0489 moles of Cu, will have (0.0489  .NA)/ 1 = 2.94x10²² atoms of Cu

8 0
2 years ago
Olympic cyclist fill their tires with helium to make them lighter. Calculate the mass of air in an air filled tire and the mass
inn [45]

<u>Answer:</u> The mass difference between the two is 7.38 grams.

<u>Explanation:</u>

To calculate the number of moles, we use the equation given by ideal gas follows:

PV=nRT

where,

P = pressure = 125 psi = 8.50 atm    (Conversion factor:  1 atm = 14.7 psi)

V = Volume = 855 mL = 0.855 L    (Conversion factor:  1 L = 1000 mL)

T = Temperature = 25^oC=[25+273]K=298K

R = Gas constant = 0.0821\text{ L. atm }mol^{-1}K^{-1}

n = number of moles = ?

Putting values in above equation, we get:

8.50atm\times 0.855L=n\times 0.0821\text{ L atm }mol^{-1}K^{-1}\times 298K\\\\n=\frac{8.50\times 0.855}{0.0821\times 298}=0.297mol

To calculate the number of moles, we use the equation:

\text{Number of moles}=\frac{\text{Given mass}}{\text{Molar mass}}      .....(1)

  • <u>For air:</u>

Moles of air = 0.297 moles

Average molar mass of air = 28.8 g/mol

Putting values in equation 1, we get:

0.297mol=\frac{\text{Mass of air}}{28.8g/mol}\\\\\text{Mass of air}=(0.297mol\times 28.8g/mol)=8.56g

Mass of air, m_1 = 8.56 g

  • <u>For helium gas:</u>

Moles of helium = 0.297 moles

Molar mass of helium = 4 g/mol

Putting values in equation 1, we get:

0.297mol=\frac{\text{Mass of helium}}{4g/mol}\\\\\text{Mass of helium}=(0.297mol\times 4g/mol)=1.18g

Mass of helium, m_2 = 1.18 g

Calculating the mass difference between the two:

\Delta m=m_1-m_2

\Delta m=(8.56-1.18)g=7.38g

Hence, the mass difference between the two is 7.38 grams.

5 0
2 years ago
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