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guapka [62]
1 year ago
13

When 1.04g of cyclopropane was burnt in excess oxygen in a bomb calorimeter, the temperature rose by 3.69K. The total heat capac

ity of the calorimeter and it's contents was 14.01kJ/K. Determine the enthalpy of combustion of cyclopropane.
Chemistry
1 answer:
STatiana [176]1 year ago
4 0

Answer:

\Delta _{comb}H=-2,093\frac{kJ}{mol}

Explanation:

Hello!

In this case, since these calorimetry problems are characterized by the fact that the calorimeter absorbs the heat released by the combustion of the substance, we can write:

Q_{rxn}+Q_{cal}=0

Thus, given the temperature change and the total heat capacity, we obtain the following total heat of reaction:

Q_{rxn}=-14.01kJ/K*3.69K\\\\Q_{rxn}=-51.70kJ

Now, by dividing by the moles in 1.04 g of cyclopropane (42.09 g/mol) we obtain the enthalpy of combustion of this fuel:

n=\frac{1.04g}{42.09g/mol}=0.0247mol\\\\\Delta _{comb}H=\frac{Q_{rxn}}{n}\\\\  \Delta _{comb}H=-2,093\frac{kJ}{mol}

Best regards!

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Using only the following elements P, Br, and Mg, give the formulas for:A. an ionic compound. B. a molecular compound with polar
Talja [164]

Answer:

<h2>1. Ionic compound- MgBr_2</h2><h2>2. Polar molecular compound- PBr_3</h2>

Explanation:

Mg is a metal that has 12 atomic numbers and thus its electronic configuration is 1s^22s^22p^63s^2. The outer most shell of this element has 2 electrons so it loses 2 electrons and thus form Mg^2^+ ions. Br is a nonmetal and has 35 atomic number so its electronic configuration is 1s^22s^22p^63s^23p^64s^23d^1^04p^5. Since its outermost shell has 7 electrons so it can accept one electron and thus forms Br^-. So magnesium ion and bromide ion combine and forms an ionic compound MgBr_2.

P is also a nonmetal and combine with Br with covalent bond and due to electronegativity differences form polar covalent compound such as PBr_3.

8 0
1 year ago
Four balloons, each with a mass of 10.0 g, are inflated to a volume of 20.0 L, each with a different gas: helium, neon, carbon m
weeeeeb [17]
On temperature 25°C (298,15K) and pressure of 1 atm each gas has same amount of substance:
n(gas) = p·V ÷ R·T = 1 atm · 20L ÷ <span>0,082 L</span>·<span>atm/K</span>·<span>mol </span>· 298,15 K
n(gas) = 0,82 mol.
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d(He) = 10 g + 3,28 g ÷ 20 L = 0,664 g/L.
2) m(Ne) = 0,82 mol · 20,17 g/mol = 16,53 g.
d(Ne) = 26,53 g ÷ 20 L = 1,27 g/L.
3) m(CO) = 0,82 mol ·28 g/mol = 22,96 g.
d(CO) = 32,96 g ÷ 20L = 1,648 g/L.
4) m(NO) = 0,82 mol ·30 g/mol = 24,6 g.
d(NO) = 34,6 g ÷ 20 L = 1,73 g/L.
6 0
2 years ago
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Rank the compounds by the ease with which they ionize under sn1 conditions. rank the compounds from easiest to hardest. to rank
marysya [2.9K]
The rate of Formation of Carbocation mainly depends on two factors'

                    1)  Stability of Carbocation:
                                                              The ease of formation of Carbocation mainly depends upon the ionization of substrate. If the forming carbocation id tertiary then it is more stable and hence readily formed as compared to secondary and primary.

                     2) Ease of detaching of Leaving Group:
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                                            R-I > R-Cl > R-F

                                               B   >  C  >  A

3 0
2 years ago
In a chemistry lab, you have two vinegars. one is 5% acetic acid, and one is 6.5% acetic acid. you want to make 200 ml of a vine
nexus9112 [7]
Assume that the amount needed from the 5% acid is x and that the amount needed from the 6.5% acid is y.

We are given that:
The volume of the final solution is 200 ml
This means that:
x + y = 200
This can be rewritten as:
x = 200 - y .......> equation I

We are also given that:
The concentration of the final solution is 6%
This means that:
5%x + 6.5%y = 6% (x+y)
This can be rewritten as:
0.05 x + 0.065 y = 0.06 (x+y) ............> equation II

Substitute with equation I in equation II and solve for y as follows:
0.05 x + 0.065 y = 0.06 (x+y)
0.05 (200-y) + 0.065 y = 0.06 (200-y+y)
10 - 0.05 y + 0.065 y = 12
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y = 2/0.015
y = 133.3334 ml

Substitute with the y in equation I to get the x as follows:
x = 200 - y
x = 200 - 133.3334
x = 66.6667 ml

Based on the above calculations:
The amount required from the 5% acid = x = 66.6667 ml
The amount required from the 6.5% acid = y = 133.3334 ml

Hope this helps :)

6 0
2 years ago
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shusha [124]

Answer:

See explanation

Explanation:

% optical purity = specific rotation of mixture/specific rotation of pure enantiomer  * 100/1

specific rotation of mixture = 23°

specific rotation of pure enantiomer = 61°

Hence;

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Enantiomeric excess = 62 - 50/50 * 100 = 24%

Hence

(R) - carvone  =  38 %

(S) - carvone = 62%

7 0
1 year ago
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