solution:
Weight of caffeine is W = 0.170 gm.
Volume of water is V= 10 ml
Volume of methylene chloride which extracted caffeine is v= 5ml
No of portions n=3
Distribution co-efficient= 4.6
Total amount of caffeine that can be unextracted is given by
![w_{n}=w\times[\frac{k_{Dx}v}{k_{Dx}v+v}]^n\\w_{3}=0.170[\frac{4.6\times10}{(4.6\times10+5)}]^3\\=0.170[\frac{46}{46+5}]^3\\=0.170[\frac{46}{51}]^3\\=0.170[\frac{97336}{132651}]\\=0.170\times0.734=0.125gms](https://tex.z-dn.net/?f=w_%7Bn%7D%3Dw%5Ctimes%5B%5Cfrac%7Bk_%7BDx%7Dv%7D%7Bk_%7BDx%7Dv%2Bv%7D%5D%5En%5C%5C%3C%2Fp%3E%3Cp%3Ew_%7B3%7D%3D0.170%5B%5Cfrac%7B4.6%5Ctimes10%7D%7B%284.6%5Ctimes10%2B5%29%7D%5D%5E3%5C%5C%3C%2Fp%3E%3Cp%3E%3D0.170%5B%5Cfrac%7B46%7D%7B46%2B5%7D%5D%5E3%5C%5C%3C%2Fp%3E%3Cp%3E%3D0.170%5B%5Cfrac%7B46%7D%7B51%7D%5D%5E3%5C%5C%3C%2Fp%3E%3Cp%3E%3D0.170%5B%5Cfrac%7B97336%7D%7B132651%7D%5D%5C%5C%3C%2Fp%3E%3Cp%3E%3D0.170%5Ctimes0.734%3D0.125gms)
amount of caffeine un extracted is 0.125gms
amount of caffeine extracted=0.170-0.125
=0.045 gms

Nitrogen lone pair will act as a base,removing H+ from water leaving behind OH- ion.
Why ?
Because N is a better donor than O.
Basis: 100 mL solution
From the given density, we calculate for the mass of the solution.
density = mass / volume
mass = density x volume
mass = (1.83 g/mL) x (100 mL) = 183 grams
Then, we calculate for the mass H2SO4 given the percentage.
mass of H2SO4 = (183 grams) x (0.981) = 179.523 grams
Calculate for the number of moles of H2SO4,
moles H2SO4 = (179.523 grams) / (98.079 g/mol)
moles H2SO4 = 1.83 moles
Molarity:
M = moles H2SO4 / volume solution (in L)
= 1.83 moles / (0.1L ) = 18.3 M
Molality:
m = moles of H2SO4 / kg of solvent
= 1.83 moles / (183 g)(1-0.983)(1 kg/ 1000 g) = 588.24 m
Answer: The empirical formula of the compound is 
Explanation:
Empirical formula is defined formula which is simplest integer ratio of number of atoms of different elements present in the compound.
Percentage of iron in a compound = 36.76 %
Percentage of sulfur in a compound = 21.11 %
Percentage of oxygen in a compound = 42.13 %
Consider in 100 g of the compound:
Mass of iron in 100 g of compound = 36.76 g
Mass of iron in 100 g of compound = 21.11 g
Mass of iron in 100 g of compound = 42.13 g
Now calculate the number of moles each element:
Moles of iron=
Moles of sulfur=
Moles of oxygen=
Divide the moles of each element by the smallest number of moles to calculated the ratio of the elements to each other
For Iron element = 
For sulfur element =
For oxygen element = 
So, the empirical formula of the compound is 
If it is heated while it is being compressed or held inside a container as such, the pressure build up while in the container and the pressure can become so much that the container will burst.