Answer:
<span>23.6
g carbon dioxide comes from 8.6 g of CH4 or 10.7 g carbon dioxide comes from
15.6 g O that means the 15.6 g of oxygen is still the limiting reactant because
it gets used up and only makes 10.7 g of CO2. </span>
Explanation:
1) Balanced chemical equation:
CH₄ + 2O₂ → CO₂ + 2H₂O
2) mole ratios:
1 mol CH₄ : 2mol O₂ : 1 mol CO₂ : 2 mol H₂O
3) molar masses
CH₄: 16.04 g/mol
O₂: 32.0 g/mol
CO₂: 44.01 g/mol
4) Convert the reactant masses to number of moles, using the formula
number of moles = mass in grams / molar mass
CH₄: 8.6g / 16.04 g/mol = 0.5362 moles
<span />
O₂: 15.6 g / 32.0 g/mol = 0.4875 moles
5) If the whole 0.5632 moles of CH₄ reacted that yields to the same number of moles of CO₂ and that is a mass of:
mass of CO₂ = number of moles x molar mass = 23.60 g of CO₂
Which is what the first part of the answer says.
6) If the whole 0.4875 moles of O₂ reacted that would yield 0.4875 / 2 = 0.24375 moles of CO₂, and that is a mass of:
mass of CO₂ = 0.4875 grams x 44.01 g/mol = 10.7 grams of CO₂.
Which is what the second part of the answer says.
7) From the mole ratio you know infere that 0.5362 moles of CH₄ needs more twice number of moles of O₂, that is 1.0724 moles of O₂, and since there are only 0.4875 moles of O₂, this is the limiting reactant.
Which is what the chosen answer says.
8) From the mole ratios 0.4875 moles of O₂ produce 0.4875 / 2 moles of CO₂, and that is:
0.4875 / 2 mols x 44.01 g/mol = 10.7 g of CO₂, which is the last part of the answer.
Answer:
2K+(aq) + CO3²¯(aq) + Ca^2+(aq) + 2F¯(aq) —› Cu2CO3(s) + 2K+(aq) + 2F¯(aq)
Explanation:
K2CO3(aq) + 2CuF(aq) → Cu2CO3(s) + 2KF(aq)
The complete ionic equation for the above equation can be written as follow:
In solution, K2CO3 and CuF will dissociate as follow:
K2CO3(aq) —› 2K+(aq) + CO3²¯(aq)
CuF(aq) —› Ca^2+(aq) + 2F¯(aq)
Thus, we can write the complete ionic equation for the reaction as shown below:
K2CO3(aq) + 2CuF(aq) —›
2K+(aq) + CO3²¯(aq) + Ca^2+(aq) + 2F¯(aq) —› Cu2CO3(s) + 2K+(aq) + 2F¯(aq)
Answer:
The correct answer is option C, that is, ΔS and ΔSsurr for the process H2O (s) ⇒ H2O(l) are equal in magnitude and opposite in sign.
Explanation:
The temperature at which solid state of water get transformed into liquid state is termed as the melting point of 0 °C. It can be shown by the reaction:
H2O (s) ⇒ H2O (l)
The degree of randomness of a molecule is known as entropy. With the transformation of ice into liquid state, there is an increase in randomness. Thus, the value of entropy becomes positive as shown:
Entropy change (ΔSsys) = ΔSproduct - ΔSreactant
= (69.9 - 47.89) J mol/K
= 22.0 J mol/K
Therefore, the value of entropy change is positive.
Now the value of entropy for surrounding ΔSsurr will be,
ΔSsurr = -ΔHfusion/T
= -6012 j/mol/273
= -22.0 J/molK
Hence, the value of ΔSsurr and ΔSsys exhibit same magnitude with opposite sign.
