Answer:
4. The combined volume of the Ar atoms is too large to be negligible compared with the total volume of the container.
Explanation:
Deviations from ideality are due to intermolecular forces and to the nonzero volume of the molecules themselves. At infinite volume, the volume of the molecules themselves is negligible compared with the infinite volume the gas occupies.
However, the volume occupied by the gas molecules must be taken into account. Each <u>molecule does occupy a finite, although small, intrinsic volume.</u>
The non-zero volume of the molecules implies that instead of moving in a given volume V they are limited to doing so in a smaller volume. Thus, the molecules will be closer to each other and repulsive forces will dominate, resulting in greater pressure than the one calculated with the ideal gas law, that means, without considering the volume occupied by the molecules.
When heat energy is supplied to a material it can raise the temperature of mass of the material.
Specific heat is the amount of energy required by 1 g of material to raise the temperature by 1 °C.
equation is
H = mcΔt
H - heat energy
m - mass of material
c - specific heat of the material
Δt - change in temperature
substituting the values in the equation
120 J = 10 g x c x 5 °C
c = 2.4 Jg⁻¹°C⁻¹
Answer : The pH of 0.289 M solution of lithium acetate at
is 9.1
Explanation :
First we have to calculate the value of
.
As we know that,

where,
= dissociation constant of an acid = 
= dissociation constant of a base = ?
= dissociation constant of water = 
Now put all the given values in the above expression, we get the dissociation constant of a base.


Now we have to calculate the concentration of hydroxide ion.
Formula used :
![[OH^-]=(K_b\times C)^{\frac{1}{2}}](https://tex.z-dn.net/?f=%5BOH%5E-%5D%3D%28K_b%5Ctimes%20C%29%5E%7B%5Cfrac%7B1%7D%7B2%7D%7D)
where,
C is the concentration of solution.
Now put all the given values in this formula, we get:
![[OH^-]=(5.5\times 10^{-10}\times 0.289)^{\frac{1}{2}}](https://tex.z-dn.net/?f=%5BOH%5E-%5D%3D%285.5%5Ctimes%2010%5E%7B-10%7D%5Ctimes%200.289%29%5E%7B%5Cfrac%7B1%7D%7B2%7D%7D)
![[OH^-]=1.3\times 10^{-5}M](https://tex.z-dn.net/?f=%5BOH%5E-%5D%3D1.3%5Ctimes%2010%5E%7B-5%7DM)
Now we have to calculate the pOH.
![pOH=-\log [OH^-]](https://tex.z-dn.net/?f=pOH%3D-%5Clog%20%5BOH%5E-%5D)


Now we have to calculate the pH.

Therefore, the pH of 0.289 M solution of lithium acetate at
is 9.1
<u>Answer:</u> The value of
for the given reaction is 1.435
<u>Explanation:</u>
To calculate the molarity of solution, we use the equation:

Given mass of
= 9.2 g
Molar mass of
= 92 g/mol
Volume of solution = 0.50 L
Putting values in above equation, we get:

For the given chemical equation:

<u>Initial:</u> 0.20
<u>At eqllm:</u> 0.20-x 2x
We are given:
Equilibrium concentration of
= 0.057
Evaluating the value of 'x'

The expression of
for above equation follows:
![K_c=\frac{[NO_2]^2}{[N_2O_4]}](https://tex.z-dn.net/?f=K_c%3D%5Cfrac%7B%5BNO_2%5D%5E2%7D%7B%5BN_2O_4%5D%7D)
![[NO_2]_{eq}=2x=(2\times 0.143)=0.286M](https://tex.z-dn.net/?f=%5BNO_2%5D_%7Beq%7D%3D2x%3D%282%5Ctimes%200.143%29%3D0.286M)
![[N_2O_4]_{eq}=0.057M](https://tex.z-dn.net/?f=%5BN_2O_4%5D_%7Beq%7D%3D0.057M)
Putting values in above expression, we get:

Hence, the value of
for the given reaction is 1.435
The equilibrium constant Kc for this reaction is calculated as follows
from the equation N2 + 3H2 =2 NH3
qc = (NH3)2/{(N2)(H2)^3}
Qc is therefore = ( 0.001)2 /{(0.1) (0.05)^3} = 0.08