Answer:
molecular weight (Mb) = 0.42 g/mol
Explanation:
mass sample (solute) (wb) = 58.125 g
mass sln = 750.0 g = mass solute + mass solvent
∴ solute (b) unknown nonelectrolyte compound
∴ solvent (a): water
⇒ mb = mol solute/Kg solvent (nb/wa)
boiling point:
- ΔT = K*mb = 100.220°C ≅ 373.22 K
∴ K water = 1.86 K.Kg/mol
⇒ Mb = ? (molecular weight) (wb/nb)
⇒ mb = ΔT / K
⇒ mb = (373.22 K) / (1.86 K.Kg/mol)
⇒ mb = 200.656 mol/Kg
∴ mass solvent = 750.0 g - 58.125 g = 691.875 g = 0.692 Kg
moles solute:
⇒ nb = (200.656 mol/Kg)*(0.692 Kg) = 138.83 mol solute
molecular weight:
⇒ Mb = (58.125 g)/(138.83 mol) = 0.42 g/mol
Concentration is the number of moles of solute in a fixed volume of solution
Concentration(c) = number of moles of solute(n) / volume of solution (v)
25.0 mL of water is added to 125 mL of a 0.150 M LiOH solution and solution becomes more diluted.
original solution molarity - 0.150 M
number of moles of LiOH in 1 L - 0.150 mol
number of LiOH moles in 0.125 L - 0.150 mol/ L x 0.125 L = 0.01875 mol
when 25.0 mL is added the number of moles of LiOH will remain constant but volume of the solution increases
new volume - 125 mL + 25 mL = 150 mL
therefore new molarity is
c = 0.01875 mol / 0.150 L = 0.125 M
answer is 0.125 M
Absorbance is related to the concentration of a substance using the Beer-Lambert's Law. According to this law, absorbance is linearly related to concentration. However, this is only true up to a certain concentration depending on the substance. For this case, we assume that the said law is applicable.
A = kC
Using the first conditions, ewe solve for k.
0.26 = k (0.10)
k = 2.6
A = kC
A = 2.6 (0.20) = 0.52
Therefore, the absorbance at a concentration of 0.20 M and wavelength of 500nm is 0.52.
Answer:
NaI > Na2SO4 > Co Br3
meaning that NaI has the highest freezing point, and Co Br3 has the lowest freezing point.
Explanation:
The freezing point depression is a colligative property.
That means that it depends on the number of solute particles dissolved.
The formula to calculate the freezing point depression of a solution of a non volatile solute is:
ΔTf = i * Kf * m
Where kf is a constant, m is the molality and i is the van't Hoff factor.
Molality, which is number of moles per kg of solvent, counts for the number of moles dissolved and the van't Hoff factor multipllies according for molecules that dissociate.
The higher the number of molecules that dissociate, the higher the van't Hoff, the greater the freezing point depression and the lower the freezing point.
As the question states that you assume equal concentrations (molality) and complete dissociation you just must find the number of ions generated by each solute, in this way:
NH4 I → NH4(+) + I(-) => 2 ions
Co Br3 → Co(+) + 3 Br(-) => 4 ions
Na2SO4 → 2Na(+) + SO4(2-) => 3 ions.
So, Co Br3 is the solute that generate more particles and that solution will exhibit the lowest freezing point among the options given, Na2SO4 is next and the NaI is the third. Ordering the freezing point from higher to lower the rank is NaI > Na2SO4 > CoBr3, which is the answer given.
Molarity = number of moles of solute/liters of solution
number of moles of solute = molarity x liters of solution
Part (a): <span>30.00 ml of 0.100m Cacl2
number of moles of CaCl2 = 0.1 x 0.03 = 3x10^-3 moles
1 mole of CaCl2 contains 2 moles of chlorine, therefore 3x10^-3 moles of CaCl2 contains 6x10^-3 moles of chlorine
Part (b): </span><span>10.0 ml of 0.500m bacl2
number of moles of BaCl2 = 0.5 x 0.01 = 5x10^-3 moles
1 mole of BaCl2 contains 2 moles of chlorine, therefore 5x10^-3 moles of BaCl2 contains 10x10^-3 moles of chlorine
Part (c): </span><span>4.00 ml of 1.000m nacl
number of moles of NaCl = 1 x 0.004 = 0.004 moles
1 mole of NaCl contains 1 mole of chlorine, therefore 4x10^-3 moles of NaCl contains 4x10^-3 moles of chlorine
Part (d): </span><span>7.50 ml of 0.500m fecl3
number of moles of FeCl3 = 0.5 x 0.0075 = 3.75x10^-3 moles
1 mole of FeCl3 contains 3 moles of chlorine, therefore 3.75x10^-3 moles of FeCl3 contains 0.01125 moles of chlorine
Based on the above calculations, the correct answer is (d)</span>
