A group of environmentalists were discussing the benefits and drawbacks associated with using fossil fuels. Which argument <span>best </span>fits the conversation?
Fossil fuels are cheaper than alternative forms of energy.Fossil fuel reserves will never be depleted.<span>Fossil fuels are easily renewed. </span><span>Fossil fuel use does not affect the environment.</span>
Answer:
4 g after 58.2 years
0.0156 After 291 years
Explanation:
Given data:
Half-life of strontium-90 = 29.1 years
Initially present: 16g
mass present after 58.2 years =?
Mass present after 291 years =?
Solution:
Formula:
how much mass remains =1/ 2n (original mass) ……… (1)
Where “n” is the number of half lives
to find n
For 58.2 years
n = 58.2 years /29.1 years
n= 2
or 291 years
n = 291 years /29.1 years
n= 10
Put values in equation (1)
Mass after 58.2 years
mass remains =1/ 22 (16g)
mass remains =1/ 4 (16g)
mass remains = 4g
Mass after 58.2 years
mass remains =1/ 210 (16g)
mass remains =1/ 1024 (16g)
mass remains = 0.0156g
To determine the Keq, we need the chemical reaction in the system. In this case it would be:
CO + 2H2 = CH3OH
The Keq is the ration of the amount of the product and the reactant. We use the ICE table for this. We do as follows:
CO H2 CH3OH
I .42 .42 0
C -0.13 -2(0.13) 0.13
-----------------------------------------------
E = .29 0.16 0.13
Therefore,
Keq = [CH3OH] / [CO2] [H2]^2 = 0.13 / 0.29 (0.16^2)
Keq = 17.51
Mass of methanol (CH3OH) = 1.922 g
Change in Temperature (t) = 4.20°C
Heat capacity of the bomb plus water = 10.4 KJ/oC
The heat absorbed by the bomb and water is equal to the product of the heat capacity and the temperature change.
Let’s assume that no heat is lost to the surroundings. First, let’s calculate the heat changes in the calorimeter. This is calculated using the formula shown below:
qcal = Ccalt
Where, qcal = heat of reaction
Ccal = heat capacity of calorimeter
t = change in temperature of the sample
Now, let’s calculate qcal:
qcal = (10.4 kJ/°C)(4.20°C)
= 43.68 kJ
Always qsys = qcal + qrxn = 0,
qrxn = -43.68 kJ
The heat change of the reaction is - 43.68 kJ which is the heat released by the combustion of 1.922 g of CH3OH. Therefore, the conversion factor is: