Answer:
![\mathbf{s =\sqrt [3]{\dfrac{K_{sp}}{4}}}](https://tex.z-dn.net/?f=%5Cmathbf%7Bs%20%3D%5Csqrt%20%5B3%5D%7B%5Cdfrac%7BK_%7Bsp%7D%7D%7B4%7D%7D%7D)
Less than the concentration of Pb2+(aq) in the solution in part ( a )
Explanation:
From the question:
A)
We assume that s to be the solubility of PbI₂.
The equation of the reaction is given as :
PbI₂(s) ⇌ Pb²⁺(aq) + 2I⁻(aq); Ksp = 7 × 10⁻⁹
[Pb²⁺] = s
Then [I⁻] = 2s
![K_{sp} =\text{[Pb$^{2+}$][I$^{-}$]}^{2} = s\times (2s)^{2} = 4s^{3}\\s^{3} = \dfrac{K_{sp}}{4}\\\\s =\mathbf{ \sqrt [3]{\dfrac{K_{sp}}{4}}}\\\\\text{The mathematical expressionthat can be used to determine the value of }\mathbf{s =\sqrt [3]{\dfrac{K_{sp}}{4}}}](https://tex.z-dn.net/?f=K_%7Bsp%7D%20%3D%5Ctext%7B%5BPb%24%5E%7B2%2B%7D%24%5D%5BI%24%5E%7B-%7D%24%5D%7D%5E%7B2%7D%20%3D%20s%5Ctimes%20%282s%29%5E%7B2%7D%20%3D%20%204s%5E%7B3%7D%5C%5Cs%5E%7B3%7D%20%3D%20%5Cdfrac%7BK_%7Bsp%7D%7D%7B4%7D%5C%5C%5C%5Cs%20%3D%5Cmathbf%7B%20%5Csqrt%20%5B3%5D%7B%5Cdfrac%7BK_%7Bsp%7D%7D%7B4%7D%7D%7D%5C%5C%5C%5C%5Ctext%7BThe%20mathematical%20expressionthat%20can%20be%20used%20to%20determine%20the%20value%20of%20%20%7D%5Cmathbf%7Bs%20%3D%5Csqrt%20%5B3%5D%7B%5Cdfrac%7BK_%7Bsp%7D%7D%7B4%7D%7D%7D)
B)
The Concentration of Pb²⁺ in water is calculated as :
![\mathbf{s =\sqrt [3]{\dfrac{7*10^{-9}}{4}}}](https://tex.z-dn.net/?f=%5Cmathbf%7Bs%20%3D%5Csqrt%20%5B3%5D%7B%5Cdfrac%7B7%2A10%5E%7B-9%7D%7D%7B4%7D%7D%7D)
![\mathbf{s} =\sqrt[3]{1.75*10^{-9}}](https://tex.z-dn.net/?f=%5Cmathbf%7Bs%7D%20%3D%5Csqrt%5B3%5D%7B1.75%2A10%5E%7B-9%7D%7D)
The Concentration of Pb²⁺ in 1.0 mol·L⁻¹ NaI
The equilibrium constant:
![K_{sp} =[Pb^{2+}}][I^-]^2 \\ \\ K_{sp} = s*(1.0*2s)^2 =7*1.0^{-9} \\ \\ s = 7*10^{-9} \ \ m/L](https://tex.z-dn.net/?f=K_%7Bsp%7D%20%3D%5BPb%5E%7B2%2B%7D%7D%5D%5BI%5E-%5D%5E2%20%5C%5C%20%5C%5C%20K_%7Bsp%7D%20%3D%20s%2A%281.0%2A2s%29%5E2%20%3D7%2A1.0%5E%7B-9%7D%20%5C%5C%20%5C%5C%20s%20%3D%207%2A10%5E%7B-9%7D%20%5C%20%5C%20%20m%2FL)
It is now clear that maximum possible concentration of Pb²⁺ in the solution is less than that in the solution in part (A). This happens due to the common ion effect. The added iodide ion forces the position of equilibrium to shift to the left, reducing the concentration of Pb²⁺.
Answer:
"statement 2" for the first pair and "statement 1" for the second pair
Explanation:
Answer:
VP as function of time => VP(Ar) > VP(Ne) > VP(He).
Explanation:
Effusion rate of the lighter particles will be higher than the heavier particles. That is, the lighter particles will leave the container faster than the heavier particles. Over time, the vapor pressure of the greater number of heavier particles will be higher than the vapor pressure of the lighter particles.
=> VP as function of time => VP(Ar) > VP(Ne) > VP(He).
Review Graham's Law => Effusion Rate ∝ 1/√formula mass.
Answer:
The answer is: Law of multiple proportions
Explanation:
The law of multiple proportions is a law of chemical combination given by Dalton in 1803.
According to this law, if more than one chemical compound is formed by combining two elements, then the mass of an element that combines with the fixed mass of other element is represented in the form of small whole number ratio.
<u>Therefore, is an illustration of the law of the law of multiple proportions.</u>
