Rydberg Eqn is given as:
1/λ = R [1/n1^2 - 1/n2^2]
<span>Where λ is the wavelength of the light; 2626 nm = 2.626×10^-6 m </span>
<span>R is the Rydberg constant: R = 1.09737×10^7 m-1 </span>
<span>From Brackett series n1 = 4 </span>
<span>Hence 1/(2.626×10^-6 ) = 1.09737× 10^7 [1/4^2 – 1/n2^2] </span>
<span>Some rearranging and collecting up terms: </span>
<span>1 = (2.626×10^-6)×(1.09737× 10^7)[1/16 -1/n2^2] </span>
<span>1= 28.82[1/16 – 1/n2^2] </span>
<span>28.82/n^2 = 1.8011 – 1 = 0.8011 </span>
<span>n^2 = 28.82/0.8011 = 35.98 </span>
<span>n = √(35.98) = 6</span>
Answer:
Equilibrium constant for 
is 0.5
Equilibrium constant for decomposition of 
is 
Explanation:
dissociates as follows:
initial 0.72 mol 0 0
at eq. 0.72 - 0.40 0.40 0.40
Expression for the equilibrium constant is as follows:
![k=\frac{[PCl_3][Cl_2]}{[PCl_5]}](https://tex.z-dn.net/?f=k%3D%5Cfrac%7B%5BPCl_3%5D%5BCl_2%5D%7D%7B%5BPCl_5%5D%7D)
Substitute the values in the above formula to calculate equilibrium constant as follows:
![k=\frac{[0.40/1][0.40/1]}{0.32/1} \\=\frac{0.40 \times 0.40}{0.32} \\=0.5](https://tex.z-dn.net/?f=k%3D%5Cfrac%7B%5B0.40%2F1%5D%5B0.40%2F1%5D%7D%7B0.32%2F1%7D%20%5C%5C%3D%5Cfrac%7B0.40%20%5Ctimes%200.40%7D%7B0.32%7D%20%5C%5C%3D0.5)
Therefore, equilibrium constant for is 0.5
Now calculate the equilibrium constant for decomposition of
It is given that 
is decomposed.
decomposes as follows:
initial 1.0 M 0 0
at eq. concentration of is:
![[NO_2]_{eq}=1-(0.000066) = 0.999934\ M](https://tex.z-dn.net/?f=%5BNO_2%5D_%7Beq%7D%3D1-%280.000066%29%20%3D%200.999934%5C%20M)
![[NO]_{eq}=6.6 \times 10^{-5}\ M](https://tex.z-dn.net/?f=%5BNO%5D_%7Beq%7D%3D6.6%20%5Ctimes%2010%5E%7B-5%7D%5C%20M)
![[O_2]_{eq}=3.3\times 10^{-5} = 3.3\times 10^{-5}\ M](https://tex.z-dn.net/?f=%5BO_2%5D_%7Beq%7D%3D3.3%5Ctimes%2010%5E%7B-5%7D%20%3D%203.3%5Ctimes%2010%5E%7B-5%7D%5C%20M)
Expression for equilibrium constant is as follows:
![K=\frac{[NO]^2[O_2]}{[NO_2]^2}](https://tex.z-dn.net/?f=K%3D%5Cfrac%7B%5BNO%5D%5E2%5BO_2%5D%7D%7B%5BNO_2%5D%5E2%7D)
Substitute the values in the above expression
![K=\frac{[6.6\times 10^{-5}]^2[3.3 \times 10^{-5}]}{[0.999934]^2} \\=1.79\times 10^{-14}](https://tex.z-dn.net/?f=K%3D%5Cfrac%7B%5B6.6%5Ctimes%2010%5E%7B-5%7D%5D%5E2%5B3.3%20%5Ctimes%2010%5E%7B-5%7D%5D%7D%7B%5B0.999934%5D%5E2%7D%20%5C%5C%3D1.79%5Ctimes%2010%5E%7B-14%7D)
Equilibrium constant for decomposition of is
Answer:
The doctor is discussing an Ocular Hypertension disease.
Explanation:
If we have a small space with a defined volume like in this case an eye, when we fill this space with a liquid, the liquid will occupy the whole volume available, and when it is much liquid or fluid, and the volume of the eye can not expand it will start to generate an internal pressure. This higher pressure is called Hypertension.
About 2,500 grams Ans balkfdoaks;
When preparing diluted solutions from concentrated solutions , we can use the following equation;
c1v1 =c2v2
Where c1 and v1 are the concentration and volume of the concentrated solution
c2 is the concentration of the diluted solution to be prepared
v2 is the volume of the diluted solution
Substituting the values;
12.0 M x v1 = 0.339 M x 100 mL
v1 = 2.825 mL needs to be taken from the stock solution
