Answer:
(a) Constitutional Isomers
(b) Constitutional Isomers
Explanation:
Constitutional isomers are also known with the name Structural Isomers. These are the compounds which have same chemical formula but differ in arrangement of atoms i.e. structure.
Both the compounds <em>cis-1,3-dibromocyclohexane</em> and <em>trans-1,4-dibromocyclohexane</em> have the same chemical formula 
but have different structure as shown in the image below.
In the second case the compounds <em>2,3-dimethylhexane</em> and <em>2,3,3-trimethylpentane</em>, both have same chemical formula 
but have different structures which is shown in the image below.
Thus it is clear that in both the groups (a) and (b) the given compounds are Constitutional Isomers.
Answer: 
Explanation:
cM 0 0
So dissociation constant will be:
Given: c = 0.15 M
pH = 1.86
= ?
Putting in the values we get:
Also ![pH=-log[H^+]](https://tex.z-dn.net/?f=pH%3D-log%5BH%5E%2B%5D)
![1.86=-log[H^+]](https://tex.z-dn.net/?f=1.86%3D-log%5BH%5E%2B%5D)
![[H^+]=0.01](https://tex.z-dn.net/?f=%5BH%5E%2B%5D%3D0.01)
![[H^+]=c\times \alpha](https://tex.z-dn.net/?f=%5BH%5E%2B%5D%3Dc%5Ctimes%20%5Calpha)
As ![[H^+]=[ClCH_2COO^-]=0.01](https://tex.z-dn.net/?f=%5BH%5E%2B%5D%3D%5BClCH_2COO%5E-%5D%3D0.01)
![K_a=1.67\times 10^{-3]](https://tex.z-dn.net/?f=K_a%3D1.67%5Ctimes%2010%5E%7B-3%5D)
Thus the vale of for the acid is
Answer is: volume of helium is 244.72 liters.
m(He) = 43.7 g.
n(He) = m(He) ÷ M(He).
n(He) = 43.7 g ÷ 4 g/mol.
n(He) = 10.925 mol.
V(He) = n(He) · n(He).
V(He) = 10.925 mol · 22.4 L/mol.
V(He) = 244.72 L.
Vm - molar volume at STP.
n - amount of substance.
excess hydrogen ions can break chemical bonds
, can change the shape of large complex molecules, rendering them nonfunctional and can disrupt tissue function.
