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2 years ago

Write equations that show the processes that describe the first, second, and third ionization energies for a gaseous iron atom.

1 answer:

7 0

The ionization energy of an element is the amount of energy required to remove one mole of electrons from the element in its gaseous state. The equations for the first three are:

Fe(g) → Fe⁺(g) + e⁻

Fe⁺(g) → Fe⁺²(g) + e⁻

Fe⁺²(g) → Fe⁺³(g) + e

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Determine the number of moles and mass requested for each reaction in Exercise 4.42.

suter [353]

Answer:

(a) 0.22 mol Cl₂ and 15.4g Cl₂

(b) 2.89.10⁻³ mol O₂ and 0.092g O₂

(d) 1,666 mol CO₂ and 73,333 g CO₂

(e) 18.87 CuCO₃ and 2,330g CuCO₃

Explanation:

In most stoichiometry problems there are a few steps that we always need to follow.

Step 1: Write the balanced equation
Step 2: Establish the theoretical relationship between the kind of information we have and the one we are looking for. Those relationships can be found in the balanced equation.
Step 3: Apply conversion factor/s to the data provided in the task based on the relationships we found in the previous step.

(a)

Step 1:

2 Na + Cl₂ ⇄ 2 NaCl

Step 2:

In the balanced equation there are 2 moles of Na, thus 2 x 23g = 46g of Na. 46g of Na react with 1 mol of Cl₂. Since the molar mass of Cl₂ is 71g/mol, then 46g of Na react with 71g of Cl₂.

Step 3:

$10.0gNa.\frac{1molCl_{2} }{46gNa} =0.22molCl_{2}$

$10.0gNa.\frac{71gCl_{2}}{46gNa} =15.4gCl_{2}$

(b)

Step 1:

HgO ⇄ Hg + 0.5 O₂

Step 2:

216.5g of HgO form 0.5 moles of O₂. 216.5g of HgO form 16g of O₂.

Step 3:

$1.252gHgO.\frac{0.5molO_{2}}{216.5gHgO} =2.89.10^{-3} molO_{2}$

$1.252gHgO.\frac{16gO_{2}}{216.5gHgO} =0.092gO_{2}$

(c)

Step 1:

NaNO₃ ⇄ NaNO₂ + 0.5 O₂

Step 2:

16g of O₂ come from 1 mol of NaNO₃. 16g of O₂ come from 85g of NaNO₃.

Step 3:

$128gO_{2}.\frac{1molNaNO_{3}}{16gO_{2}} =8mol NaNO_{3}$

$128gO_{2}.\frac{85gNaNO_{3}}{16gO_{2}} =680gNaNO_{3}$

(d)

Step 1:

C + O₂ ⇄ CO₂

Step 2:

12 g of C form 1 mol of CO₂. 12 g of C form 44g of CO₂.

Step 3:

$20.0kgC.\frac{1,000gC}{1kgC} .\frac{1molCO_{2}}{12gC} =1,666molCO_{2$

$[tex]20.0kgC.\frac{1,000gC}{1kgC} .\frac{44gCO_{2}}{12gC} =73,333gCO_{2$ [/tex]

(e)

Step 1:

CuCO₃ ⇄ CuO + CO₂

Step 2:

79.5g of CuO come from 1 mol of CuCO₃. 79.5g of CuO come from 123.5g of CuCO₃.

Step 3:

$1.500kgCuO.\frac{1,000gCuO}{1kgCuO} .\frac{1mol CuCO_{3}}{79.5gCuO} =18.87molCuCO_{3}\\ 1.500kgCuO.\frac{1,000gCuO}{1kgCuO} .\frac{123.5g CuCO_{3}}{79.5gCuO} =2,330gCuCO_{3}$

5 0

2 years ago

Marie discovers boxes of elements in a storage room. The boxes do not say which elements they contain, but they do have informat

Mazyrski [523]

The elements in a Periodic Table are grouped according to their classifications. The major classifications are Metals, Non-metals, and Metalloids. Their level of reactivity can be gauged by simply looking at their position in the table. For Metals, their reactivity increases as you move to the left then going down. Non-metal reactivity increases as you move to the right then going up, starting at the bottom of the table.

5 0

2 years ago

Read 2 more answers

When 9.2 g of frozen N2O4 is added to a 0.50 L reaction vessel and the vessel is heated to 400 K and allowed to come to equilibr

Amanda [17]

Answer: The value of $K_c$ for the given reaction is 1.435

Explanation:

To calculate the molarity of solution, we use the equation:

$\text{Molarity of the solution}=\frac{\text{Mass of solute}}{\text{Molar mass of solute}\times \text{Volume of solution (in L)}}$

Given mass of $N_2O_4$ = 9.2 g

Molar mass of $N_2O_4$ = 92 g/mol

Volume of solution = 0.50 L

Putting values in above equation, we get:

$\text{Molarity of solution}=\frac{9.2g}{92g/mol\times 0.50L}\\\\\text{Molarity of solution}=0.20M$

For the given chemical equation:

$N_2O_4(g)\rightleftharpoons 2NO_2(g)$

Initial: 0.20

At eqllm: 0.20-x 2x

We are given:

Equilibrium concentration of $N_2O_4$ = 0.057

Evaluating the value of 'x'

$\Rightarrow (0.20-x)=0.057\\\\\Rightarrow x=0.143$

The expression of $K_c$ for above equation follows:

$K_c=\frac{[NO_2]^2}{[N_2O_4]}$

$[NO_2]_{eq}=2x=(2\times 0.143)=0.286M$

$[N_2O_4]_{eq}=0.057M$

Putting values in above expression, we get:

$K_c=\frac{(0.286)^2}{0.143}\\\\K_c=1.435$

Hence, the value of $K_c$ for the given reaction is 1.435

6 0

2 years ago

A sample of 8.5 g nh3 on oxidation produces 4.5 g of no. calculate the percent yield. reaction: 4 nh3 5 o2 → 4 no 6 h2o

AnnZ [28]

30.% Determine the molar mass of NH3 and NO Atomic weight nitrogen = 14.0067 Atomic weight hydrogen = 1.00794 Atomic weight oxygen = 15.999 Molar mass NH3 = 14.0067 + 3 * 1.00794 = 17.03052 g/mol Molar mass NO = 14.0067 + 15.999 = 30.0057 g/mol Moles NH3 = 8.5 / 17.03052 = 0.499103962 mol Moles NO = 4.5 / 30.0057 = 0.149971505 mol Looking at the balanced equation, for every mole of NH3 consumed, you should get one mole of NO. So if we had 100% yield, we should have 0.499103962 moles of NO. But we don't. The percent yield is a simple matter of division by what we did get by what we should get. So 0.149971505 / 0.499103962 = 0.300481497 = 30.0481497% Rounding to 2 significant figures gives 30.% yield.

5 0

2 years ago

If kc = 7.04 × 10-2 for the reaction: 2 hbr(g) ⇌h2(g) + br2(g), what is the value of kc for the reaction: 1/2 h2(g) + 1/2 br2 ⇌h

Kay [80]

At the first reaction when 2HBr(g) ⇄ H2(g) + Br2(g)
So Kc = [H2] [Br2] / [HBr]^2
7.04X10^-2 = [H2][Br] / [HBr]^2

at the second reaction when 1/2 H2(g) + 1/2 Br2 (g) ⇄ HBr
Its Kc value will = [HBr] / [H2]^1/2*[Br2]^1/2
we will make the first formula of Kc upside down:
1/7.04X10^-2 = [HBr]^2/[H2][Br2]
and by taking the square root:
∴ √(1/7.04X10^-2)= [HBr] / [H2]^1/2*[Br]^1/2
∴ Kc for the second reaction = √(1/7.04X10^-2) = 3.769

7 0

2 years ago