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eimsori [14]
2 years ago
15

You have a racemic mixture of d-2-butanol and l-2-butanol. the d isomer rotates polarized light by +13.5∘. what is the rotation

of the polarization of light of your mixture? express your answer in degrees.
Chemistry
1 answer:
Bumek [7]2 years ago
8 0
L- isomer is considered as the Enantiomer of d- isomer and since the d-isomer optical rotation is + 13.5° so the optical rotation of l-isomer will be the same degree but with opposite sign which equal to -13.5° 

So the degree of rotation of racemic mixture will equal 0° 


- This is because racemic mixture contains equal amount of both enantiomers
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Here's what I get.

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To solve this problem we need to use the <em>boiling-point elevation formula</em>:

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Where <em>Tsolution</em> and <em>Tpure solvent</em> are the boiling point of the CS₂ solution (47.52 °C) and of pure CS₂ (46.3 °C), respectively. Kb is the constant asked by the problem, and m is the molality of the solution.

So in order to use that equation and solve for Kb, first we <em>calculate the molality of the solution</em>.

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