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eimsori [14]
2 years ago
15

You have a racemic mixture of d-2-butanol and l-2-butanol. the d isomer rotates polarized light by +13.5∘. what is the rotation

of the polarization of light of your mixture? express your answer in degrees.
Chemistry
1 answer:
Bumek [7]2 years ago
8 0
L- isomer is considered as the Enantiomer of d- isomer and since the d-isomer optical rotation is + 13.5° so the optical rotation of l-isomer will be the same degree but with opposite sign which equal to -13.5° 

So the degree of rotation of racemic mixture will equal 0° 


- This is because racemic mixture contains equal amount of both enantiomers
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Classify the following as a type of potential energy or kinetic energy (use the letters K or P)
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Why nitro group is called an ambident group?​
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Answer:

The nitro group is an ambident group and is capable of getting attached to carbon chain through nitrogen. as well as through oxygen (-O - N = O) atom. The compound in which the -NO2 group is linked to the alkyl or aryl group through oxygen atom are called nitrites

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Determine the number of atoms in 1.85 ml of mercury. (the density of mercury is 13.5 g/ml.)
kati45 [8]
First step is to get the mass of the mercury:
Pressure = mass/volume
mass = pressure x volume = 13.5 x 1.85 = 24.975 gm

Second step is to calculate the number of moles in 24.975 gm:
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mass = number of moles x molar mass
number of moles = 24.975 / 200.59 = 0.1245 mole

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7 0
2 years ago
In E. coli, the enzyme hexokinase catalyzes the reaction: Glucose + ATP → glucose 6-phosphate + ADP The equilibrium constant, Ke
kondor19780726 [428]

Answer:

Explanation:

Glucose + ATP → glucose 6-phosphate + ADP The equilibrium constant, Keq, is 7.8 x 102.

In the living E. coli cells,

[ATP] = 7.9 mM;

[ADP] = 1.04 mM,

[glucose] = 2 mM,

[glucose 6-phosphate] = 1 mM.

Determine if the reaction is at equilibrium. If the reaction is not at equilibrium, determine which side the reaction favors in living E. coli cells.

The reaction is given as

Glucose + ATP → glucose 6-phosphate + ADP

Now reaction quotient for given equation above is

q=\frac{[\text {glucose 6-phosphate}][ADP]}{[Glucose][ATP]}

q=\frac{(1mm)\times (1.04 mm)}{(7.9mm)\times (2mm)} \\\\=6.582\times 10^{-2}

so,

q ⇒ following this criteria the reaction will go towards the right direction ( that is forward reaction is favorable  until q = Keq

4 0
2 years ago
If PbI2(s) is dissolved in 1.0MNaI(aq) , is the maximum possible concentration of Pb2+(aq) in the solution greater than, less th
fredd [130]

Answer:

\mathbf{s =\sqrt [3]{\dfrac{K_{sp}}{4}}}

Less than the concentration of Pb2+(aq) in the solution in part ( a )

Explanation:

From the question:

A)

We assume that s to be  the solubility of PbI₂.

The equation of the reaction is given as :

PbI₂(s) ⇌ Pb²⁺(aq) + 2I⁻(aq); Ksp = 7 × 10⁻⁹

 [Pb²⁺] =   s

Then [I⁻] = 2s

K_{sp} =\text{[Pb$^{2+}$][I$^{-}$]}^{2} = s\times (2s)^{2} =  4s^{3}\\s^{3} = \dfrac{K_{sp}}{4}\\\\s =\mathbf{ \sqrt [3]{\dfrac{K_{sp}}{4}}}\\\\\text{The mathematical expressionthat can be used to determine the value of  }\mathbf{s =\sqrt [3]{\dfrac{K_{sp}}{4}}}

B)

The Concentration of Pb²⁺  in water is calculated as :

\mathbf{s =\sqrt [3]{\dfrac{K_{sp}}{4}}}

\mathbf{s =\sqrt [3]{\dfrac{7*10^{-9}}{4}}}

\mathbf{s} =\sqrt[3]{1.75*10^{-9}}

\mathbf{s} =\mathbf{1.21*10^{-3}  \ mol/L }

The Concentration of Pb²⁺  in 1.0 mol·L⁻¹ NaI

\mathbf{PbCl{_2}}  \leftrightharpoons    \ \ \ \ \ \ \  \mathbf{Pb^{2+}}   \ \ \ \  \ +   \ \  \ \ \ \ \ \mathbf{2 I^-}

                             \ \ \ \ \ \ \  \ \   \ \  \ \ \ \ \ \ \  \mathbf0}   \ \ \ \  \ \ \ \ \ \   \ \ \ \ \ \mathbf{1.0}

                            \ \ \ \ \ \ \ \ \ \ \ \ \ \    \ \ \ \ \  \mathbf{+x}   \ \ \ \  \    \ \  \ \ \ \ \ \mathbf{+2x}

                            \ \ \ \ \ \ \ \ \ \ \ \ \ \    \ \ \ \ \  \mathbf{+x}   \ \ \ \  \    \ \  \ \ \ \ \ \mathbf{1.0+2x}

The equilibrium constant:

K_{sp} =[Pb^{2+}}][I^-]^2 \\ \\ K_{sp} = s*(1.0*2s)^2 =7*1.0^{-9} \\ \\ s = 7*10^{-9} \ \  m/L

It is now clear that maximum possible concentration of Pb²⁺ in the solution is less than that in the solution in part (A). This happens due to the  common ion effect. The added iodide ion forces the position of equilibrium to shift to the left, reducing the concentration of Pb²⁺.

3 0
2 years ago
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