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Step2247 [10]
2 years ago
13

. Citric acid, which can be obtained from lemon juice, has the molecular formula C6H8O7. A 0.250-g sample of citric acid dissolv

ed in 25.0 mL of water requires 37.2 mL of 0.105 M NaOH for complete neutralization. What number of acidic hydrogens per molecule does citric acid have?
Chemistry
1 answer:
marysya [2.9K]2 years ago
3 0

Answer:

3 acidic hydrogens per molecule of citric acid

Explanation:

In a sample of 37.2 mL(0.0372 L) of 0.105 mol/L of NaOH, will have:

n = 0.105x0.0372 = 0.0039 mol of NaOH

The dissociation of NaOH will give the same number of moles of Na⁺ and OH⁻.

The molar mass of citric acid is:

C: 12g/mol x 6 = 72 g/mol

H: 1g/mol x 8 = 8g/mol

O: 16 g/mol x 7 = 112 g/mol

192 g/mol

So, 0.250g of the acid has

n = mass/molar mass

n = 0.250/192

n = 0.0013 mol.

To be neutralized, it will be necessary 0.0039 mol of acidic hydrogens to react with the 0.0039 mol of OH⁻.

The dissociation reaction of one molecule of  the acid will give the stoichiometry:

1 mol of acid ----------------------- x mol of acidic hydrogens

0.0013 mol --------------------------- 0.0039

For a simple direct three rule:

0.0013x = 0.0039

x = 3 acidic hydrogens per molecule of citric acid.

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Cl₂O₇

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For the reaction:

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Empirical formula is the simplest ratio of atoms presents in a molecule. If Cl is <em>1</em>, Oxygen will be:

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As empirical formula must be given in natural numbers, the empirical formula is:

<em>Cl₂O₇</em>

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Explanation:

Dipole moment is defined as the measurement of the separation of two opposite electrical charges.

H_{2}O is a bent shaped molecule with a dipole moment of 1.87.

H_{2}S is also a bent shaped molecule with a dipole moment of 1.10.

H_{2}Te is a also a bent shaped molecule and has a negligible dipole moment.

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