Here we have to get the correct statements among the given, applicable for Diels-Alder reaction.
The true statements in case Diels-Alder reaction are-
1. An excess of Maleic anhydride is used.
2. The I.R. of the products are indistinguishable.
The Diels-Alder reaction is the most is the most important cyclo-addition reaction in organic chemistry. These are addition reactions in which ring systems are formed without eliminating any compounds.
There remains one diene and one dienophile. The reaction is reversible in nature and requires elevated temperature to obtain its transition state. The reaction rate become faster in certain condition like using of polar solvents.
Among the given statements the following statements are true-
1. An excess of maleic anhydride (the most effective di-enophile) is used to process the reaction in forward direction.
2. The products obtain in this reaction are stereoisomers thus are indistinguishable by infrared spectroscopy (IR).
The statements which are not true for the Diels-Alder reaction:
3. The re-crystallization of the products by any polar solvent like methanol is not feasible as it will cause the retro reaction due to stability of the transition state in polar solvent.
4. Cleaning of glassware are compulsory for any reaction it is not specifically true for Diels-Alder reaction.
5. The reaction occurs at elevated temperature thus flame is required.
Answer:
The percent yield of this reaction is 70%
Explanation:
The reaction is: N₂ + 3H₂ → 2NH₃
We only have the mass of H₂, so we assume that N₂ is in excess
We convert the mass to moles, to work with the reaction:
450 g . 1mol / 2 g = 225 moles
Ratio is 2:3. 3 moles of H₂ can produce 2 moles of ammonia
Therefore 225 moles of H₂ will produce (225 .2)/ 3 = 150 moles
This is the 100% yield reaction → We convert the moles of NH₃ to mass
150 mol . 17g /1mol = 2550 g
Percent yield = (Produced yield/Theoretical yield) .100
Percent yield = (1575g/2550g) . 100 = 70%
When the concentration is expressed in molality, it is expressed in moles of solute per kilogram of solvent. Since we are given the mass of the solvent, which is water, we can compute for the moles of solute NaNO3.
0.5 m = x mol NaNO3/0.5 kg water
x = 0.25 mol NaNO3
Since the molar mass of NaNO3 is 85 g/mol, the mass is
0.25 mol * 85 g/mol = 21.25 grams NaNO3 needed
Answer:
a. 278.4kJ/mol
b. due to resonance, some energy are released
Explanation: