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2 years ago

The rate of disappearance of HCl was measured for the following reaction:

Chemistry

1 answer:

AURORKA [14]2 years ago

6 0

Answer: (a) 0.000083M/s, 0.000069M/s, 0.000052M/s, 0.000034M/s

(b) average reaction rate between t=0.0min to t=430.0min =0.000049M/s

(c) The average rate between t=54.0 and t=215.0min is greater than the average rate between t=107.0 and t=430.0min

Explanation:

Average reaction rate = change in concentration / time taken

(a) after 54mins, t = 54*60s = 3240s

average reaction rate = (1.58 - 1.85)M / (3240 * 0.0)s

= -0.27M/3240

= 0.000083M/s

after 107mins, t = 107*60s = 6420s

average reaction rate = (1.36 - 1.58)M/ (6420 - 3240)s

= -0.22M/3180s

= 0.000069M/s

after 215mins, t = 215*60s = 12900s

average reaction rate = (1.02 - 1.36)M/ (12900 - 6420)s

= -0.34M/6480s

= 0.000052M/s

after 430mins,t = 430*60 = 25800s

average reaction rate = (0.580 - 1.02)M / (25800 - 12900)s

= -0.44M/12900s

= 0.000034M/s

(b) average reaction rate between t=0.0min to t=430.0min

= (0.580 - 1.85)M/ (25800 - 0.0)s

= -1.27M/25800s

=0.000049M/s

= (1.02 - 1.58)M / (12900 - 3240)s

= -0.56M/9660s

= 0.000058M/s

average reaction rate between t=107.0 and t=430.0min

= (0.580 - 1.36)M / (25800 - 6420)s

= 0.78M /19380s

= 0.000040M/s

Therefore the average rate between t=54.0 and t=215.0min is greater than the average rate between t=107.0 and t=430.0min

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1 year ago

Which of the following represents a propagation step in the monochlorination of methylene chloride (CH2Cl2)?a. CHCl3 + Cl. Right

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Answer:

B = CHCl2 + Cl2 --> CHCl3 + Cl

Explanation:

Free radical halogenation is a chlorination reaction on Alkane hydrocarbons. This involves the splitting of molecules into radicals/ unstable molecules in the presence of sunlight/ U.V light which ensures bonding of the molecules.

Free radical chlorination is divided into 3 steps which are:

The initiation step

The propagation step

The termination step

So in reference to the question, propagation step involves two steps.

The first step is where the molecule in this case the methylene chloride(CH2Cl2) loses a hydrogen atom and then bond with a chlorine atom radical to give a nethylwnw chloride radical and HCl.

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2 years ago

Exactly 1.0 mol N2O4 is placed in an empty 1.0-L container and allowed to reach equilibrium described by the equation N2O4(g) 2N

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Answer : The correct option is, (a) 0.44

Explanation :

First we have to calculate the concentration of $N_2O_4$ .

$\text{Concentration of }N_2O_4=\frac{\text{Moles of }N_2O_4}{\text{Volume of solution}}$

$\text{Concentration of }N_2O_4=\frac{1.0moles}{1.0L}=1.0M$

Now we have to calculate the dissociated concentration of $N_2O_4$ .

The balanced equilibrium reaction is,

$N_2O_4(g)\rightleftharpoons 2NO_2(aq)$

Initial conc. 1.0 M 0

At eqm. conc. (1.0-x) M (2x) M

As we are given,

The percent of dissociation of $N_2O_4$ = $\alpha$ = 28.0 %

So, the dissociate concentration of $N_2O_4$ = $C\alpha=1.0M\times \frac{28.0}{100}=0.28M$

The value of x = $C\alpha$ = 0.28 M

Now we have to calculate the concentration of $N_2O_4\text{ and }NO_2$ at equilibrium.

Concentration of $N_2O_4$ = 1.0 - x = 1.0 - 0.28 = 0.72 M

Concentration of $NO_2$ = 2x = 2 × 0.28 = 0.56 M

Now we have to calculate the equilibrium constant for the reaction.

The expression of equilibrium constant for the reaction will be:

$K_c=\frac{[NO_2]^2}{[N_2O_4]}$

Now put all the values in this expression, we get :

$K_c=\frac{(0.56)^2}{0.72}=0.44$

Therefore, the equilibrium constant $K_c$ for the reaction is, 0.44

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