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2 years ago

2. The diagram below shows steps in the exothermic chemical reaction of bromomethane with

Chemistry

1 answer:

vovangra [49]2 years ago

8 0

Answer:

Here's what I get

Explanation:

1. Balanced equation

HQ⁻ + CH₃-Br ⟶ HQ-CH₃ + Br⁻

(I must use HQ because the Brainly Editor thinks the O makes a forbidden word)

2. Mechanism

HQ⁻ + CH₃-Br ⟶[HQ···CH₃···Br]⁻⟶ HQ-CH₃ + Br⁻

A C B

The hydroxide ion attacks the back side of the carbon atom in the bromomethane (A).

At the same time as the Q-H bond starts to form, the C-Br bond starts to break.

At the half-way point, we have a high-energy intermediate (C) with partially formed C-O and C-Br bonds.

As the reaction proceeds further, the Br atom drops off to form the products — methanol and bromide ion (B).

3. Energy diagram

See the diagram below.

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Substitution of an amino group on the para position of acetophenone shifts the cjo frequency from about 1685 to 1652 cm−1 , wher

cluponka [151]

Answer:

Here's what I get.

Explanation:

The frequency of a vibration depends on the strength of the bond (the force constant).

The stronger the bond, the more energy is needed for the vibration, so the frequency (f) and the wavenumber increase.

Acetophenone

Resonance interactions with the aromatic ring give the C=O bond in acetophenone a mix of single- and double-bond character, and the bond frequency = 1685 cm⁻¹.

p-Aminoacetophenone

The +R effect of the amino group increases the single-bond character of the C=O bond. The bond lengthens, so it becomes weaker.

The vibrational energy decreases, so wavenumber decreases to 1652 cm⁻¹.

p-Nitroacetophenone

The nitro group puts a partial positive charge on C-1. The -I effect withdraws electrons from the acetyl group.

As electron density moves toward C-1, the double bond character of the C=O group increases.

The bond length decreases, so the bond becomes stronger, and wavenumber increases to 1693 cm¹.

6 0

2 years ago

The chemical reaction Na+ + Cl- NaCl is best described as a(n) _____.

svlad2 [7]

<span>Na + Cl = NaCl

answer : </span><span>synthesis reaction .

hope this helps!

</span>

5 0

1 year ago

Read 2 more answers

For the reaction 3h2(g) + n2(g) 2nh3(g), kc = 9.0 at 350°c. calculate g° at 350°c.

miss Akunina [59]

When ΔG° is the change in Gibbs free energy

So according to ΔG° formula:

ΔG° = - R*T*(㏑K)

here when K = [NH3]^2/[N2][H2]^3 = Kc

and Kc = 9

and when T is the temperature in Kelvin = 350 + 273 = 623 K

and R is the universal gas constant = 8.314 1/mol.K

So by substitution in ΔG° formula:

∴ ΔG° = - 8.314 1/ mol.K * 623 K *㏑(9)

= - 4536

4 0

1 year ago

In acidic solution, the breakdown of sucrose into glucose and fructose has this rate law: rate = k[H+][sucrose].

Karo-lina-s [1.5K]

Answer:

a)If concentration of [Sucrose] is changed to 2.5 M than rate will be increased by the factor of 2.5.

b)If concentration of [Sucrose] is changed to 0.5 M than rate will be increased by the factor of 0.5.

c)If concentration of $[H^+]$ is changed to 0.0001 M than rate will be increased by the factor of 0.01.

d) If concentration when [sucrose] and $[H^+]$ both are changed to 0.1 M than rate will be increased by the factor of 1.

Explanation:

Sucrose + $H^+\rightarrow$ fructose+ glucose

The rate law of the reaction is given as:

$R=k[H^+][sucrose]$

$[H^+]=0.01M$

[sucrose]= 1.0 M

$R=k[0.01M][1.0 M]$ ..[1]

The rate of the reaction when [Sucrose] is changed to 2.5 M = R'

$R'=[0.01 M][2.5 M]$ ..[2]

[2] ÷ [1]

$\frac{R'}{R}=\frac{[0.01 M][2.5 M]}{k[0.01M][1.0 M]}$

$R'=2.5\times R$

If concentration of [Sucrose] is changed to 2.5 M than rate will be increased by the factor of 2.5.

The rate of the reaction when [Sucrose] is changed to 0.5 M = R'

$R'=[0.01 M][0.5 M]$ ..[2]

[2] ÷ [1]

$\frac{R'}{R}=\frac{[0.01 M][0.5 M]}{k[0.01M][1.0 M]}$

$R'=2.5\times R$

If concentration of [Sucrose] is changed to 0.5 M than rate will be increased by the factor of 0.5.

The rate of the reaction when $[H^+]$ is changed to 0.001 M = R'

$R'=[0.0001 M][1.0 M]$ ..[2]

[2] ÷ [1]

$\frac{R'}{R}=\frac{[0.0001 M][1.0M]}{k[0.01M][1.0 M]}$

$R'=0.01\times R$

If concentration of $[H^+]$ is changed to 0.0001 M than rate will be increased by the factor of 0.01.

The rate of the reaction when [sucrose] and $[H^+]$ both are changed to 0.1 M = R'

$R'=[0.1M][0.1M]$ ..[2]

[2] ÷ [1]

$\frac{R'}{R}=\frac{[0.1M][0.1M]}{k[0.01M][1.0 M]}$

$R'=1\times R$

If concentration when [sucrose] and $[H^+]$ both are changed to 0.1 M than rate will be increased by the factor of 1.

5 0

2 years ago

An atom of the element zinc has an atomic number of 30 and a mass number of 65. How many protons does an uncharged zinc atom hav

navik [9.2K]

Answer : The correct option is, 30 protons

Explanation :

Element = Zinc

Atomic number = 30

Atomic mass number = 65

As we know that the atomic number is equal to the number of electrons and number of protons.

Atomic number = Number of electrons = Number of protons = 30

Number of neutrons = Atomic mass - Number of protons = 65 - 30 = 35

Therefore, the number of protons an uncharged zinc atom have 30 protons.

6 0

2 years ago

Read 2 more answers