Answer: a. 79.6 s
b. 44.3 s
c. 191 s
Explanation:
Expression for rate law for first order kinetics is given by:
where,
k = rate constant
t = age of sample
a = let initial amount of the reactant
a - x = amount left after decay process
a) for completion of half life:
Half life is the amount of time taken by a radioactive material to decay to half of its original value.
b) for completion of 32% of reaction
c) for completion of 81 % of reaction
When we have the balanced equation for this reaction:
AB3 ↔ A+3 + 3B-
So we can get Ksp:
when Ksp = [A+3][B-]^3
when [A+3] = 0.047 mol and from the balanced equation when
1 mol [A+3] → 3 mol [B-]
0.047 [A+3] → ??
[B-] = 3*0.047 = 0.141
so by substitution in Ksp formula:
∴Ksp = 0.047 * 0.141^3
= 1.32x10^-4
Answer:
At the burner temp. and pressure, 18.85 litres of air is needed to completely combust each gram of propane
Explanation:
The combustion stoichiometry is as follows:
C₃H₈ + 5O₂ = 4 H₂O + 3CO₂ The molecular weights (g/mol) are:
MW 44 5x32 4x18 3x44
So each gram of propane is 1/44 = 0.02272 mol propane
and will need 5 x 0.02272 = 0.1136 mol oxygen
At 0.21 mol fraction oxygen in air, 0.1136 / 0.21 = 0.54 mol air is needed to burn the propane.
At the low pressure in the burner we can use the Ideal Gas Law
PV=nRT, or V = nRT/P
P = 1.1 x 101325 Pa = 111457 Pa
T = 195°C + 273 = 468 K
R = 8.314
and we calculated n = number of moles air = 0.54 mol
So V m³ = 0.54 x 8.314 x 468 / 111457 = 0.0188 m³ = 18.85 litres air.