Answer:
Q= 245 =2.5 * 10^2
Explanation:
ΔG = ΔGº + RTLnQ, so also ΔGº= - RTLnK
R= 8,314 J/molK, T=298K
ΔGº= - RTLnK = - 6659.3 J/mol = - 6.7 KJ/mol
ΔG = ΔGº + RTLnQ → -20.5KJ/mol = - 6.7 KJ/mol + 2.5KJ/mol* LnQ
→ 5.5 = LnQ → Q= 245 =2.5 * 10^2
Given reaction represents dissociation of bromine gas to form bromine atoms
Br2(g) ↔ 2Br(g)
The enthalpy of the above reaction is given as:
ΔH = ∑n(products)Δ
- ∑n(reactants)Δ
where n = number of moles
Δ
= enthalpy of formation
ΔH = [2*ΔH(Br(g)) - ΔH(Br2(g))] = 2*111.9 - 30.9 = 192.9 kJ/mol
Thus, enthalpy of dissociation is the bond energy of Br-Br = 192.9 kJ/mol
Answer:
E° = 0.65 V
Explanation:
Let's consider the following reductions and their respective standard reduction potentials.
Sn⁴⁺(aq) + 2 e⁻ → Sn²⁺(aq) E°red = 0.15 V
Ag⁺(aq) + e⁻ → Ag(s) E°red = 0.80 V
The reaction with the highest reduction potential will occur as a reduction while the other will occur as an oxidation. The corresponding half-reactions are:
Reduction (cathode): Ag⁺(aq) + e⁻ → Ag(s) E°red = 0.80 V
Oxidation (anode): Sn²⁺(aq) → Sn⁴⁺(aq) + 2 e⁻ E°red = 0.15 V
The overall cell potential (E°) is the difference between the standard reduction potential of the cathode and the standard reduction potential of the anode.
E° = E°red, cat - E°red, an = 0.80 V - 0.15 V = 0.65 V
Answer:
The possible structures are ketone and aldehyde.
Explanation:
Number of double bonds of the given compound is calculated using the below formula.
=Number of double bonds
= Number of carbon atoms
= Number of hydrogen atoms
= Number of nitrogen atoms
The number of double bonds in the given formula - 
The number of double bonds in the compound is one.
Therefore, probable structures is as follows.
(In attachment)
The structures I and III are ruled out from the probable structures because the signal in 13C-NMR appears at greater than 160 ppm.
alkene compounds I and II shows signal less than 140 ppm.
Hence, the probable structures III and IV are given as follows.
The carbonyl of structure I appear at 202 and ketone group of IV appears at 208 in 13C, which are greater than 160.
Hence, the molecular formula of the compound having possible structure in which the signal appears at greater than 160 ppm are shown aw follows.
Ideal solutions obey Raoult's law, which states that:
P_i = x_i*(P_pure)_i
where
P_i is the partial pressure of component i above a solution
x_i is the mole fraction of component i in the solution
(P_pure)_i is the vapor pressure of pure component i
In this case,
P_benzene = 0.59 * 745 torr = 439.6 torr
P_toluene = (1-0.59) * 290 torr = 118.9 torr
The total vapor pressure above the solution is the sum of the vapor pressures of the individual components:
P_total = (439.6 + 118.9) torr = 558.5 torr
Assuming the gas phase also behaves ideally, the partial pressure of each gas in the vapor phase is proportional to its molar concentration, so the mole fraction of toluene in the vapor phase is:
118.9 torr/558.5 torr = 0.213
